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Ethylbenzene

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas7.12 ± 0.20kcal/molCcbProsen, Gilmont, et al., 1945Hf by Prosen, Johnson, et al., 1946; ALS
Deltafgas11.7 ± 0.96kcal/molCcbN/AValue computed using «DELTA»fHliquid° from missing citation and «DELTA»vapH° value of 10.1 kcal/mol from missing citation. recalculated with modern CO2,H2O thermo; estimated uncertainty (NOTE all values in source also have wrong sign); DRB
Deltafgas16.6kcal/molN/AMoureu and Andre, 1914Value computed using «DELTA»fHliquid° value of 27.0 kj/mol from Moureu and Andre, 1914 and «DELTA»vapH° value of 42.3 kj/mol from Prosen, Gilmont, et al., 1945.; DRB
Quantity Value Units Method Reference Comment
gas86.2 ± 0.1cal/mol*KN/AMiller A., 1978S(298.16 K)=361.5 J/mol*K was obtained from earlier experimental data [ Guttman L., 1943].; GT

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
10.6050.Thermodynamics Research Center, 1997Recommended values are in good agreement with other statistically calculated data [ Miller A., 1978, Taylor W.J., 1946].; GT
13.80100.
17.29150.
21.16200.
27.935273.15
30.449298.15
30.638300.
40.619400.
49.374500.
56.585600.
62.502700.
67.419800.
71.551900.
75.0571000.
78.0501100.
80.6091200.
82.8111300.
84.7061400.
86.3461500.

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
38.06 ± 0.19373.15Hossenlopp I.A., 1981Heat capacities determined from acoustical measurements [ Colgate S.O., 1990] (124.98, 138.21, 158.84, and 173.88 J/mol*K at 298.15, 323.15, 373.15, and 408.15 K, respectively) are slightly lower than calorimetric ones. Please also see Scott R.B., 1945.; GT
39.257 ± 0.079385.65
40.452 ± 0.081398.15
42.772 ± 0.086423.15
45.000 ± 0.091448.15
47.168 ± 0.093473.15
49.221 ± 0.098498.15
51.15 ± 0.10523.15

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-2.98 ± 0.20kcal/molCcbProsen, Gilmont, et al., 1945Hf by Prosen, Johnson, et al., 1946; ALS
Deltafliquid1.6 ± 0.96kcal/molCcbN/Arecalculated with modern CO2,H2O thermo; estimated uncertainty (NOTE all values in source also have wrong sign); DRB
Deltafliquid6.5kcal/molCcbMoureu and Andre, 1914ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1092. ± 4.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
liquid60.949cal/mol*KN/AGuthrie, Spitzer, et al., 1944DH
liquid61.21cal/mol*KN/AHuffman, Parks, et al., 1930Extrapolation below 90 K, 61.09 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
44.17293.31Andolenko and Grigor'ev, 1979T = 293 to 393 K. Unsmoothed experimental datum given as 1.741 kJ/kg*K.; DH
44.3528298.15Fortier and Benson, 1979DH
44.3497298.15Fortier and Benson, 1977DH
44.402298.15Fortier, Benson, et al., 1976DH
38.5295.Tschamler, 1948DH
44.41298.Kurbatov, 1947T = 15 to 18 C, mean Cp, four temperatures.; DH
44.465298.15Scott and Brickwedde, 1945T = 15 to 300 K.; DH
44.410298.15Guthrie, Spitzer, et al., 1944T = 13 to 305 K.; DH
42.71302.8de Kolossowsky and Udowenko, 1934DH
42.71302.7Kolosovskii and Udovenko, 1934DH
44.60298.15Blacet, Leighton, et al., 1931T = 286 to 368 K. Heat capacity reported as 0.420 cal g-1 K-1 at 25 C.; DH
43.91298.5Smith and Andrews, 1931T = 102 to 299 K. Value is unsmoothed experimental datum.; DH
43.40297.4Huffman, Parks, et al., 1930T = 93 to 305 K. Value is unsmoothed experimental datum.; DH
43.40303.Willams and Daniels, 1924T = 303 to 343 K. Equation only.; DH
44.10298.von Reis, 1881T = 292 to 425 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil409.3 ± 0.3KAVGN/AAverage of 78 out of 97 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus179. ± 2.KAVGN/AAverage of 16 out of 17 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple178.15KN/AScott and Brickwedde, 1945, 2Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple178.KN/AHuffman, Parks, et al., 1930, 2Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tc617. ± 2.KAVGN/AAverage of 10 values; Individual data points
Quantity Value Units Method Reference Comment
Pc35.9 ± 0.9atmAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Vc0.374l/molN/ATsonopoulos and Ambrose, 1995 
Quantity Value Units Method Reference Comment
rhoc2.68 ± 0.010mol/lN/ATsonopoulos and Ambrose, 1995 
rhoc2.670mol/lN/ASimon, 1957Uncertainty assigned by TRC = 0.04 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap10. ± 1.kcal/molAVGN/AAverage of 7 values; Individual data points

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
8.501409.3N/AMajer and Svoboda, 1985 
10.155294.01N/AScott and Brickwedde, 1945DH
9.99313.AStephenson and Malanowski, 1987Based on data from 298. - 420. K.; AC
8.84424.AStephenson and Malanowski, 1987Based on data from 409. - 459. K.; AC
8.56472.AStephenson and Malanowski, 1987Based on data from 457. - 554. K.; AC
8.48564.AStephenson and Malanowski, 1987Based on data from 549. - 617. K.; AC
9.70335.N/APaul, Krug, et al., 1986Based on data from 320. - 400. K.; AC
9.68 ± 0.02328.CSvoboda, Charvátová, et al., 1982AC
9.44 ± 0.02343.CSvoboda, Charvátová, et al., 1982AC
9.23 ± 0.02358.CSvoboda, Charvátová, et al., 1982AC
9.56345.MMWillingham, Taylor, et al., 1945Based on data from 330. - 410. K. See also Forziati, Norris, et al., 1949.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kcal/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kcal/mol) beta Tc (K) Reference Comment
295. - 437.13.940.2823617.1Majer and Svoboda, 1985 

Entropy of vaporization

DeltavapS (cal/mol*K) Temperature (K) Reference Comment
34.54294.01Scott and Brickwedde, 1945DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
420.00 - 600.004.399651695.026-23.698Ambrose, Broderick, et al., 1967Coefficents calculated by NIST from author's data.
329.74 - 410.274.069171419.315-60.539Williamham, Taylor, et al., 1945 

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
2.1945178.15Scott and Brickwedde, 1945DH
2.190178.17Guthrie, Spitzer, et al., 1944DH
2.19178.2Domalski and Hearing, 1996AC
2.190178.0Huffman, Parks, et al., 1930DH

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
12.32178.15Scott and Brickwedde, 1945DH
12.29178.17Guthrie, Spitzer, et al., 1944DH
12.30178.0Huffman, Parks, et al., 1930DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C8H9- + Hydrogen cation = Ethylbenzene

By formula: C8H9- + H+ = C8H10

Quantity Value Units Method Reference Comment
Deltar406.0 ± 4.6kcal/molCIDTGraul and Squires, 1990gas phase; From decarboxylation threshold. Stable form probably the spiro[2.5]octadienide Maas and van Keelen, 1989; B
Quantity Value Units Method Reference Comment
Deltar397.7 ± 4.7kcal/molH-TSGraul and Squires, 1990gas phase; From decarboxylation threshold. Stable form probably the spiro[2.5]octadienide Maas and van Keelen, 1989; B

C8H9- + Hydrogen cation = Ethylbenzene

By formula: C8H9- + H+ = C8H10

Quantity Value Units Method Reference Comment
Deltar379.7 ± 2.1kcal/molG+TSBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Deltar373.3 ± 2.0kcal/molIMREBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B

2Hydrogen + Phenylethyne = Ethylbenzene

By formula: 2H2 + C8H6 = C8H10

Quantity Value Units Method Reference Comment
Deltar-66.12 ± 0.06kcal/molChydDavis, Allinger, et al., 1985liquid phase; solvent: Hexane; ALS
Deltar-64.7 ± 0.9kcal/molChydRogers and McLafferty, 1971liquid phase; solvent: Hydrocarbon; ALS
Deltar-70.7 ± 1.0kcal/molChydFlitcroft and Skinner, 1958liquid phase; ALS

Nitric oxide anion + Ethylbenzene = (Nitric oxide anion bullet Ethylbenzene)

By formula: NO- + C8H10 = (NO- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar44.5kcal/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Ethylbenzene + 3Hydrogen = Cyclohexane, ethyl-

By formula: C8H10 + 3H2 = C8H16

Quantity Value Units Method Reference Comment
Deltar-48.18 ± 0.10kcal/molChydDolliver, Gresham, et al., 1937gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -48.9 ± 0.1 kcal/mol; At 355 °K; ALS

Chlorine anion + Ethylbenzene = (Chlorine anion bullet Ethylbenzene)

By formula: Cl- + C8H10 = (Cl- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar5.00kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.0300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Ethylbenzene + Benzene, bromo- = C8H9Br + Benzene

By formula: C8H10 + C6H5Br = C8H9Br + C6H6

Quantity Value Units Method Reference Comment
Deltar-0.14 ± 0.0050kcal/molCmMerdzhanov, Alenin, et al., 1982gas phase; Heat of isomerization at 349 K; ALS

Styrene + Hydrogen = Ethylbenzene

By formula: C8H8 + H2 = C8H10

Quantity Value Units Method Reference Comment
Deltar-28.01 ± 0.41kcal/molChydAbboud, Jimenez, et al., 1995liquid phase; solvent: Hydrocarbon; Like gas phase; ALS

Ethylbenzene = Styrene + Hydrogen

By formula: C8H10 = C8H8 + H2

Quantity Value Units Method Reference Comment
Deltar29.840kcal/molEqkGhosh, Ram Das Guha, et al., 1945gas phase; ALS

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/kg*bar)
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/kg*bar) d(ln(kH))/d(1/T) (K) Method Reference Comment
0.125100.LN/A 
0.154600.MN/A 
0.11 QN/ASeveral references are given in the list of Henry's law constants but not assigned to specific species.
0.134600.MN/A 
0.12 QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.
0.115500.XN/A 
0.125000.XN/A 
0.161700.XN/A 
0.13 LN/A 
0.145500.XN/A 
0.12 MMackay, Shiu, et al., 1979 
0.11 TMackay, Shiu, et al., 1979 
0.12 VN/A 
0.176100.MN/A 
0.15 VBohon and Claussen, 1951 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
MM - Michael M. Meot-Ner (Mautner)
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C8H10+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)8.77 ± 0.01eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)188.3kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity181.7kcal/molN/AHunter and Lias, 1998HL

Proton affinity at 298K

Proton affinity (kcal/mol) Reference Comment
188.8Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Gas basicity at 298K

Gas basicity (review) (kcal/mol) Reference Comment
181.7Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Ionization energy determinations

IE (eV) Method Reference Comment
8.77PEHowell, Goncalves, et al., 1984LBLHLM
8.61PEKlasinc, Kovac, et al., 1983LBLHLM
8.65 ± 0.10EISelim and Helal, 1982LBLHLM
8.76EIMcLoughlin, Morrison, et al., 1979LLK
8.768 ± 0.008EQLias and Ausloos, 1978LLK
8.75 ± 0.05PIAkopyan and Vilesov, 1966RDSH
8.76 ± 0.01PIWatanabe, Nakayama, et al., 1962RDSH
8.77 ± 0.01SHammond, Price, et al., 1950RDSH
8.77PEHowell, Goncalves, et al., 1984Vertical value; LBLHLM
8.73PEKlasinc, Kovac, et al., 1983Vertical value; LBLHLM
9.38PEDeshmukh, Dutta, et al., 1982Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C5H5+16.2 ± 0.2C2H2+CH3EITajima and Tsuchiya, 1973LLK
C6H6+11.0 ± 0.1C2H4?PIAkopyan and Vilesov, 1966RDSH
C7H7+9.9 ± 0.1CH3TRPILifshitz and Malinovich, 1984LBLHLM
C7H7+10.15 ± 0.10CH3EISelim and Helal, 1982LBLHLM
C7H7+10.06CH3EIMcLoughlin, Morrison, et al., 1979LLK
C7H7+10.9 ± 0.1CH3PIAkopyan and Vilesov, 1966RDSH
C8H9+10.60HEIMcLoughlin, Morrison, et al., 1979LLK
C8H9+12.1 ± 0.1HPIAkopyan and Vilesov, 1966RDSH
C8H9+11.4 ± 0.1HEIMeyer, Haynes, et al., 1965RDSH

De-protonation reactions

C8H9- + Hydrogen cation = Ethylbenzene

By formula: C8H9- + H+ = C8H10

Quantity Value Units Method Reference Comment
Deltar406.0 ± 4.6kcal/molCIDTGraul and Squires, 1990gas phase; From decarboxylation threshold. Stable form probably the spiro[2.5]octadienide Maas and van Keelen, 1989; B
Quantity Value Units Method Reference Comment
Deltar397.7 ± 4.7kcal/molH-TSGraul and Squires, 1990gas phase; From decarboxylation threshold. Stable form probably the spiro[2.5]octadienide Maas and van Keelen, 1989; B

C8H9- + Hydrogen cation = Ethylbenzene

By formula: C8H9- + H+ = C8H10

Quantity Value Units Method Reference Comment
Deltar379.7 ± 2.1kcal/molG+TSBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Deltar373.3 ± 2.0kcal/molIMREBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Ethylbenzene = (Chlorine anion bullet Ethylbenzene)

By formula: Cl- + C8H10 = (Cl- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar5.00kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.0300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Nitric oxide anion + Ethylbenzene = (Nitric oxide anion bullet Ethylbenzene)

By formula: NO- + C8H10 = (NO- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar44.5kcal/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Data compiled by: Pamela M. Chu, Franklin R. Guenther, George C. Rhoderick, and Walter J. Lafferty


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 114918

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Prosen, Gilmont, et al., 1945
Prosen, E.J.; Gilmont, R.; Rossini, F.D., Heats of combustion of benzene, toluene, ethyl-benzene, o-xylene, m-xylene, p-xylene, n-propylbenzene, and styrene, J. Res. NBS, 1945, 34, 65-70. [all data]

Prosen, Johnson, et al., 1946
Prosen, E.J.; Johnson, W.H.; Rossini, F.D., Heats of combustion and formation at 25°C of the alkylbenzenes through C10H14, and of the higher normal monoalkylbenzenes, J. Res. NBS, 1946, 36, 455-461. [all data]

Moureu and Andre, 1914
Moureu, C.; Andre, E., Thermochimie des composes acetyleniques, Ann. Chim. Phys., 1914, 1, 113-145. [all data]

Miller A., 1978
Miller A., Chemical thermodynamic properties of ethylbenzene, J. Chem. Phys., 1978, 68, 1317-1319. [all data]

Guttman L., 1943
Guttman L., Jr., The thermodynamics of styrene (phenylethylene), including equilibrium of formation from ethylbenzene, J. Am. Chem. Soc., 1943, 65, 1246-1247. [all data]

Thermodynamics Research Center, 1997
Thermodynamics Research Center, Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]

Taylor W.J., 1946
Taylor W.J., Heats, equilibrium constants, and free energies of formation of the alkylbenzenes, J. Res. Nat. Bur. Stand., 1946, 37, 95-122. [all data]

Hossenlopp I.A., 1981
Hossenlopp I.A., Vapor heat capacities and enthalpies of vaporization of four aromatic and/or cycloalkane hydrocarbons, J. Chem. Thermodyn., 1981, 13, 423-428. [all data]

Colgate S.O., 1990
Colgate S.O., Acoustical determination of ideal gas heat capacities of three C-8 compounds, Fluid Phase Equilib., 1990, 60, 191-203. [all data]

Scott R.B., 1945
Scott R.B., Specific heats of gaseous 1,3-butadiene, isobutene, styrene, and ethylbenzene, J. Res. Nat. Bur. Stand., 1945, 34, 243-254. [all data]

Guthrie, Spitzer, et al., 1944
Guthrie, G.B., Jr.; Spitzer, R.W.; Huffman, H.M., Thermal data. XVIII. The heat capacity, heat of fusion, entropy and free energy of ethylbenzene, J. Am. Chem. Soc., 1944, 66, 2120-2121. [all data]

Huffman, Parks, et al., 1930
Huffman, H.M.; Parks, G.S.; Daniels, A.C., Thermal data on organic compounds. VII. The heat capacities, entropies and free energies of twelve aromatic hydrocarbons, J. Am. Chem. Soc., 1930, 52, 1547-1558. [all data]

Andolenko and Grigor'ev, 1979
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Fortier and Benson, 1979
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Notes

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