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Benzene, (bromomethyl)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil471.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil471.KN/ABuckingham and Donaghy, 1982BS
Tboil471.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Tfus271.75KN/AAshcroft, 1976Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap53.3 ± 0.7kJ/molGSKrasnykh, Vasiltsova, et al., 2002Based on data from 284. - 306. K.; AC
Deltavap53.7kJ/molCGCKrasnykh, Vasiltsova, et al., 2002AC
Deltavap50.5 ± 0.5kJ/molN/AAshcroft, 1976, 2AC
Deltavap47.3 ± 4.2kJ/molVBenson and Buss, 1957ALS

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
400.0.11Buckingham and Donaghy, 1982BS
400.0.11Buckingham and Donaghy, 1982BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
46.9320.AStephenson and Malanowski, 1987Based on data from 305. - 472. K. See also Stull, 1947 and Dykyj, Svoboda, et al., 1999.; AC
48.1355.I,AAshcroft, 1976, 2Based on data from 340. - 409. K. See also Stephenson and Malanowski, 1987.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
305.4 - 471.74.673422043.135-34.57Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
13.2271.8Ashcroft, 1976, 2AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Ashcroft, 1976
Ashcroft, S.J., J. Chem. Eng. Data, 1976, 21, 397. [all data]

Krasnykh, Vasiltsova, et al., 2002
Krasnykh, Eugen L.; Vasiltsova, Tatiana V.; Verevkin, Sergey P.; Heintz, Andreas, Vapor Pressures and Enthalpies of Vaporization of Benzyl Halides and Benzyl Ethers, J. Chem. Eng. Data, 2002, 47, 6, 1372-1378, https://doi.org/10.1021/je020034h . [all data]

Ashcroft, 1976, 2
Ashcroft, Stanley J., Vapor pressures and enthalpies of vaporization of benzyl halides, J. Chem. Eng. Data, 1976, 21, 4, 397-398, https://doi.org/10.1021/je60071a009 . [all data]

Benson and Buss, 1957
Benson, S.W.; Buss, J.H., The thermodynamics of bromination of toluene and the heat of formation of the benzyl radical, J. Phys. Chem., 1957, 61, 104-109. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]


Notes

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