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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)11.94 ± 0.03eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
11.94 ± 0.03PIBerkowitz, Greene, et al., 1984LBLHLM
12.0 ± 0.1EIFoner and Hudson, 1973LLK
12.04 ± 0.10EIHerron and Dibeler, 1960RDSH
12.84PECornford, Frost, et al., 1971Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FN+16.6NF2+FEIFoner and Hudson, 1973LLK
FN2+14.2 ± 0.3F2+FEIFoner and Hudson, 1973LLK
FN2+16.7 ± 0.33FEIFoner and Hudson, 1973LLK
F2N+12.565 ± 0.010NF2PIBerkowitz, Greene, et al., 1984LBLHLM
F2N+12.7 ± 0.1NF2EIFoner and Hudson, 1973LLK
F2N+12.4 ± 0.1F(-)+NFEIFoner and Hudson, 1973LLK
NF2+12.6 ± 0.1NF2EICristy and Mamantov, 1970RDSH
NF2+12.7 ± 0.2NF2EIHerron and Dibeler, 1960RDSH
F2N2+16.0 ± 0.12FEIFoner and Hudson, 1973LLK
N2F3+12.0F-EIHerron and Dibeler, 1961RDSH
N2F3+15.6FEIHerron and Dibeler, 1961RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Greene, et al., 1984
Berkowitz, J.; Greene, J.P.; Foropoulos, J., Jr.; Neskovic, O.M., Bonding and ionization energies of N-F and P-F compounds, J. Chem. Phys., 1984, 81, 6166. [all data]

Foner and Hudson, 1973
Foner, S.N.; Hudson, R.L., Mass spectrometric studies of tetrafluorohydrazine and the difluoroamino radical, J. Chem. Phys., 1973, 58, 581. [all data]

Herron and Dibeler, 1960
Herron, J.T.; Dibeler, V.H., Mass spectrum and appearance potentials of tetrafluorohydrazine, J. Chem. Phys., 1960, 33, 1595. [all data]

Cornford, Frost, et al., 1971
Cornford, A.B.; Frost, D.C.; Herring, F.G.; McDowell, C.A., Ionization potentials of the difluoroamino radical by photoelectron spectroscopy and INDO calculations, J. Chem. Phys., 1971, 54, 1872. [all data]

Cristy and Mamantov, 1970
Cristy, S.S.; Mamantov, G., Cryogenic mass spectrometry of reactive fluorine-containing species. II. Applications to synthesis via pyrolysis, photolysis and microwave discharge, Intern. J. Mass Spectrom. Ion Phys., 1970, 5, 319. [all data]

Herron and Dibeler, 1961
Herron, J.T.; Dibeler, V.H., Mass spectrometric study of NF2, NF3, N2F2, and N2F4, J. Res. NBS, 1961, 65A, 405. [all data]


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