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cobalt trifluoride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Fluorine anion + cobalt trifluoride = (Fluorine anion bullet cobalt trifluoride)

By formula: F- + CoF3 = (F- bullet CoF3)

Quantity Value Units Method Reference Comment
Deltar442. ± 25.kJ/molTDAsRau, Chilingarov, et al., 1997gas phase; Values are at 0K; value altered from reference due to conversion from electron convention to ion convention
Deltar441.0 ± 8.4kJ/molTDEqSidorov, Nikulin, et al., 1987gas phase; Fluoride Affinity: 11.2 kcal/mol < AlF3; value altered from reference due to conversion from electron convention to ion convention

AlF4- + cobalt trifluoride = (AlF4- bullet cobalt trifluoride)

By formula: AlF4- + CoF3 = (AlF4- bullet CoF3)

Quantity Value Units Method Reference Comment
Deltar230. ± 50.kJ/molTherSidorov, Nikulin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rau, Chilingarov, et al., 1997
Rau, J.V.; Chilingarov, N.S.; Sidorov, L.N., Mass spectrometric determination of cobalt trifluoride saturated vapor pressure. Enthalpy of formation of gaseous CoF4, and CoF4-, Rapid Commun. Mass Spectrom., 1997, 11, 18, 1977-1979, https://doi.org/10.1002/(SICI)1097-0231(199712)11:18<1977::AID-RCM808>3.0.CO;2-J . [all data]

Sidorov, Nikulin, et al., 1987
Sidorov, L.N.; Nikulin, V.V.; Chilingarov, N.S.; Korobov, M.V., The Enthalpy of Formation of the CoF4- Ion in the Gas Phase, Russ. J. Phys. Chem., 1987, 61, 555. [all data]


Notes

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