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phosphorus pentachloride


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   D3h     Symmetry Number sigma = 6


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1' 1 PCl3 s-str 395  D 395 VS p solid solid solid solid
a1' 2 PCl2 s-str 370  D 370 VW dp solid solid solid solid
a2 3 PCl2 a-str 465  C 465 VS gas 441 VW dp solid solid solid solid
a2 4 PCl3 op-deform 299  D 299 S solid solid 301 solid solid solid solid
e' 5 PCl3 d-str 592  C 592 VS gas 581 W p solid solid solid solid
e' 6 PCl3 d-deform 273  D 273 S solid solid 281 W dp solid solid solid solid
e' 7 PCl bend 100  C 100 W gas 100 M dp solid solid solid solid
e 8 PCl bend 261  D 261 W dp solid solid solid solid

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
WWeak
VWVery weak
pPolarized
dpDepolarized
C3~6 cm-1 uncertainty
D6~15 cm-1 uncertainty

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

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