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antimony trichloride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, M. Frenkel director

Quantity Value Units Method Reference Comment
Tc798.KN/ASladkov and Shimeleva, 1974Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Vc0.254l/molN/ASladkov and Shimeleva, 1974Uncertainty assigned by TRC = 0.005 l/mol; Abstract, no details; TRC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
322.4 - 492.3.269121200.884-125.836Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Phase change data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Cl3Sb = Cl4Sb-

By formula: Cl- + Cl3Sb = Cl4Sb-

Quantity Value Units Method Reference Comment
Deltar160. ± 7.9kJ/molCIDTWalker, Check, et al., 2002gas phase

Gas phase ion energetics data

Go To: Top, Phase change data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - S.G. Lias, J.E. Bartmess, J.F. Liebman, J.L. Holmes, R.D. Levin, and W.G. Mallard
LLK - S.G. Lias, R.D. Levin, and S.A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
11.0 ± 0.1EIOzgen, 1983LBLHLM
10.73PENicholson and Rademacher, 1974Vertical value; LLK
10.70PELee and Rabalais, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ClSb+12.5 ± 0.1Cl2/2ClEIOzgen, 1983LBLHLM
Cl2Sb+11.8 ± 0.1ClEIOzgen, 1983LBLHLM

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Cl3Sb = Cl4Sb-

By formula: Cl- + Cl3Sb = Cl4Sb-

Quantity Value Units Method Reference Comment
Deltar160. ± 7.9kJ/molCIDTWalker, Check, et al., 2002gas phase

References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sladkov and Shimeleva, 1974
Sladkov, I.B.; Shimeleva, V.I., Russ. J. Phys. Chem. (Engl. Transl.), 1974, 48, 154. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Walker, Check, et al., 2002
Walker, B.W.; Check, C.E.; Lobring, K.C.; Pommerening, C.A.; Sunderlin, L.S., The Thermochemistry of Group 15 Tetrachloride Anions, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 469, https://doi.org/10.1016/S1044-0305(02)00369-0 . [all data]

Ozgen, 1983
Ozgen, T., Mass spectrometric determination of the appearance potentials of PCl3, AsCl3, SbCl3, BiCl3 and their fragments, Int. J. Mass Spectrom. Ion Processes, 1983, 48, 427. [all data]

Nicholson and Rademacher, 1974
Nicholson, D.G.; Rademacher, P., Photoelectron spectra and electronic structures of antimony(III) halides, Acta Chem. Scand. Ser. A:, 1974, 28, 1136. [all data]

Lee and Rabalais, 1974
Lee, T.H.; Rabalais, J.W., Model for spin- orbit interactions with inclusion of d electrons: Applications to photoelectron spectroscopy, J. Chem. Phys., 1974, 60, 1172. [all data]


Notes

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