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Nitrous oxide

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Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas19.61kcal/molReviewChase, 1998Data last reviewed in December, 1964
Quantity Value Units Method Reference Comment
gas,1 bar52.572cal/mol*KReviewChase, 1998Data last reviewed in December, 1964

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 1400.1400. - 6000.
A 6.61565114.41270
B 12.224900.247267
C -7.324221-0.046127
D 1.6366910.002997
E -0.037741-1.639641
F 17.0290011.61900
G 57.0306965.12911
H 19.6100019.61000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1964 Data last reviewed in December, 1964

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Nitric oxide anion + Nitrous oxide = (Nitric oxide anion bullet Nitrous oxide)

By formula: NO- + N2O = (NO- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar10. ± 30.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar18.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Deltar14.9cal/mol*KDTIllies, 1988gas phase; «DELTA»rH(0 K)=7.70 kcal/mol; M

NO2+ + Nitrous oxide = (NO2+ bullet Nitrous oxide)

By formula: NO2+ + N2O = (NO2+ bullet N2O)

Quantity Value Units Method Reference Comment
Deltar14.1kcal/molEICameron, Aitken, et al., 1994gas phase; M
Deltar17.4kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Deltar13.1 ± 0.8kcal/molDTIllies, 1988gas phase; «DELTA»rH(0 K)=13.3 kcal/mol; M
Deltar13.1kcal/molPILinn and Ng, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Deltar12.4cal/mol*KDTIllies, 1988gas phase; «DELTA»rH(0 K)=13.3 kcal/mol; M

Oxygen cation + Nitrous oxide = (Oxygen cation bullet Nitrous oxide)

By formula: O2+ + N2O = (O2+ bullet N2O)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Deltar10.7 ± 0.4kcal/molDTIllies, 1988gas phase; «DELTA»rH(0 K)=10.8 kcal/mol; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Deltar15.3cal/mol*KDTIllies, 1988gas phase; «DELTA»rH(0 K)=10.8 kcal/mol; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.9200.FAAdams and Bohme, 1970gas phase; switching reaction(O2+)O2; M

(Iodide bullet 2Nitrous oxide) + Nitrous oxide = (Iodide bullet 3Nitrous oxide)

By formula: (I- bullet 2N2O) + N2O = (I- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar2.7 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar3.2kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar15.cal/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Nitric oxide anion bullet Nitrous oxide) + Nitrous oxide = (Nitric oxide anion bullet 2Nitrous oxide)

By formula: (NO- bullet N2O) + N2O = (NO- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar5.90 ± 0.90kcal/molN/AHendricks, de Clercq, et al., 2002gas phase; B
Deltar4.60kcal/molN/ACoe, Snodgrass, et al., 1987gas phase; B
Deltar5.6kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar6.kcal/molPESCoe, Snodgrass, et al., 1986gas phase; D(N2O)2 not accounted for; M
Quantity Value Units Method Reference Comment
Deltar-1.0 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion bullet 2Nitrous oxide) + Nitrous oxide = (Nitric oxide anion bullet 3Nitrous oxide)

By formula: (NO- bullet 2N2O) + N2O = (NO- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar5.20 ± 0.90kcal/molN/AHendricks, de Clercq, et al., 2002gas phase; B
Deltar5.1kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-1.2 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Iodide bullet Nitrous oxide) + Nitrous oxide = (Iodide bullet 2Nitrous oxide)

By formula: (I- bullet N2O) + N2O = (I- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar2.9 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar3.3 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.2cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Iodide + Nitrous oxide = (Iodide bullet Nitrous oxide)

By formula: I- + N2O = (I- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar2.7 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar3.8 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.1cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

HN2O+ + Nitrous oxide = (HN2O+ bullet Nitrous oxide)

By formula: HN2O+ + N2O = (HN2O+ bullet N2O)

Quantity Value Units Method Reference Comment
Deltar16.7kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Deltar20.6kcal/molPHPMSSzulejko and McMahon, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Deltar31.5cal/mol*KPHPMSSzulejko and McMahon, 1992gas phase; M

(Oxygen anion bullet 2Nitrous oxide) + Nitrous oxide = (Oxygen anion bullet 3Nitrous oxide)

By formula: (O2- bullet 2N2O) + N2O = (O2- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar6.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-0.8 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion bullet 3Nitrous oxide) + Nitrous oxide = (Oxygen anion bullet 4Nitrous oxide)

By formula: (O2- bullet 3N2O) + N2O = (O2- bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar5.70 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-1.5 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion bullet 4Nitrous oxide) + Nitrous oxide = (Oxygen anion bullet 5Nitrous oxide)

By formula: (O2- bullet 4N2O) + N2O = (O2- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar5.30 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-1.9 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion bullet 5Nitrous oxide) + Nitrous oxide = (Oxygen anion bullet 6Nitrous oxide)

By formula: (O2- bullet 5N2O) + N2O = (O2- bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar5.00 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.2 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- bullet 2Nitrous oxide) + Nitrous oxide = (O- bullet 3Nitrous oxide)

By formula: (O- bullet 2N2O) + N2O = (O- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar5.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-0.9 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- bullet 3Nitrous oxide) + Nitrous oxide = (O- bullet 4Nitrous oxide)

By formula: (O- bullet 3N2O) + N2O = (O- bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar5.20 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.0 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- bullet 4Nitrous oxide) + Nitrous oxide = (O- bullet 5Nitrous oxide)

By formula: (O- bullet 4N2O) + N2O = (O- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar5.20 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- bullet 5Nitrous oxide) + Nitrous oxide = (O- bullet 6Nitrous oxide)

By formula: (O- bullet 5N2O) + N2O = (O- bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar5.10 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.7 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- bullet 6Nitrous oxide) + Nitrous oxide = (O- bullet 7Nitrous oxide)

By formula: (O- bullet 6N2O) + N2O = (O- bullet 7N2O)

Quantity Value Units Method Reference Comment
Deltar5.10 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar28.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-3.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(O- bullet Nitrous oxide) + Nitrous oxide = (O- bullet 2Nitrous oxide)

By formula: (O- bullet N2O) + N2O = (O- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar5.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-0.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Oxygen anion bullet Nitrous oxide) + Nitrous oxide = (Oxygen anion bullet 2Nitrous oxide)

By formula: (O2- bullet N2O) + N2O = (O2- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar8.70 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar27.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.6 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

Oxygen anion + Nitrous oxide = (Oxygen anion bullet Nitrous oxide)

By formula: O2- + N2O = (O2- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar<13.60kcal/molIMRBAdams and Bohme, 1970gas phase; N2O..O2- + O2 -> O4- + N2O; B
Deltar8.8kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

(Nitric oxide anion bullet 3Nitrous oxide) + Nitrous oxide = (Nitric oxide anion bullet 4Nitrous oxide)

By formula: (NO- bullet 3N2O) + N2O = (NO- bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar5.00 ± 0.90kcal/molN/AHendricks, de Clercq, et al., 2002gas phase; B
Deltar4.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-1.2 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion bullet 4Nitrous oxide) + Nitrous oxide = (Nitric oxide anion bullet 5Nitrous oxide)

By formula: (NO- bullet 4N2O) + N2O = (NO- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar4.20 ± 0.90kcal/molN/AHendricks, de Clercq, et al., 2002gas phase; B
Deltar4.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-1.5 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Hydronium cation bullet 3Nitrous oxide) + Nitrous oxide = (Hydronium cation bullet 4Nitrous oxide)

By formula: (H3O+ bullet 3N2O) + N2O = (H3O+ bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar5.2kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M

(NO2+ bullet 5Nitrous oxide) + Nitrous oxide = (NO2+ bullet 6Nitrous oxide)

By formula: (NO2+ bullet 5N2O) + N2O = (NO2+ bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar3.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M

(HN2O+ bullet 5Nitrous oxide) + Nitrous oxide = (HN2O+ bullet 6Nitrous oxide)

By formula: (HN2O+ bullet 5N2O) + N2O = (HN2O+ bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar4.8kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar30.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated; M

(Chlorine anion bullet 4Nitrous oxide) + Nitrous oxide = (Chlorine anion bullet 5Nitrous oxide)

By formula: (Cl- bullet 4N2O) + N2O = (Cl- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar4.8kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Fluorine anion bullet 6Nitrous oxide) + Nitrous oxide = (Fluorine anion bullet 7Nitrous oxide)

By formula: (F- bullet 6N2O) + N2O = (F- bullet 7N2O)

Quantity Value Units Method Reference Comment
Deltar3.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(NO2+ bullet 2Nitrous oxide) + Nitrous oxide = (NO2+ bullet 3Nitrous oxide)

By formula: (NO2+ bullet 2N2O) + N2O = (NO2+ bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar2.8kcal/molEICameron, Aitken, et al., 1994gas phase; M
Deltar5.6kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ bullet Nitrous oxide) + Nitrous oxide = (NO2+ bullet 2Nitrous oxide)

By formula: (NO2+ bullet N2O) + N2O = (NO2+ bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar5.1kcal/molEICameron, Aitken, et al., 1994gas phase; M
Deltar5.7kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Nitric oxide anion bullet 5Nitrous oxide) + Nitrous oxide = (Nitric oxide anion bullet 6Nitrous oxide)

By formula: (NO- bullet 5N2O) + N2O = (NO- bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar4.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M,M
Quantity Value Units Method Reference Comment
Deltar-1.9 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion bullet 6Nitrous oxide) + Nitrous oxide = (Nitric oxide anion bullet 7Nitrous oxide)

By formula: (NO- bullet 6N2O) + N2O = (NO- bullet 7N2O)

Quantity Value Units Method Reference Comment
Deltar4.20 ± 0.30kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M,M
Quantity Value Units Method Reference Comment
Deltar-2.7 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

Methyl cation + Nitrous oxide = (Methyl cation bullet Nitrous oxide)

By formula: CH3+ + N2O = (CH3+ bullet N2O)

Quantity Value Units Method Reference Comment
Deltar52.9kcal/molPHPMSMcMahon, Heinis, et al., 1988gas phase; switching reaction(CH3+)N2, Entropy change calculated or estimated, uses MCA(N2) = 48.3 kcal/mol; Foster, Williamson, et al., 1974; M

(Iodide bullet 10Nitrous oxide) + Nitrous oxide = (Iodide bullet 11Nitrous oxide)

By formula: (I- bullet 10N2O) + N2O = (I- bullet 11N2O)

Quantity Value Units Method Reference Comment
Deltar1.0 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 11Nitrous oxide) + Nitrous oxide = (Iodide bullet 12Nitrous oxide)

By formula: (I- bullet 11N2O) + N2O = (I- bullet 12N2O)

Quantity Value Units Method Reference Comment
Deltar1.3 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 9Nitrous oxide) + Nitrous oxide = (Iodide bullet 10Nitrous oxide)

By formula: (I- bullet 9N2O) + N2O = (I- bullet 10N2O)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 3Nitrous oxide) + Nitrous oxide = (Iodide bullet 4Nitrous oxide)

By formula: (I- bullet 3N2O) + N2O = (I- bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar2.8 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 4Nitrous oxide) + Nitrous oxide = (Iodide bullet 5Nitrous oxide)

By formula: (I- bullet 4N2O) + N2O = (I- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar2.7 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 5Nitrous oxide) + Nitrous oxide = (Iodide bullet 6Nitrous oxide)

By formula: (I- bullet 5N2O) + N2O = (I- bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 6Nitrous oxide) + Nitrous oxide = (Iodide bullet 7Nitrous oxide)

By formula: (I- bullet 6N2O) + N2O = (I- bullet 7N2O)

Quantity Value Units Method Reference Comment
Deltar2.2 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 7Nitrous oxide) + Nitrous oxide = (Iodide bullet 8Nitrous oxide)

By formula: (I- bullet 7N2O) + N2O = (I- bullet 8N2O)

Quantity Value Units Method Reference Comment
Deltar2.1 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 8Nitrous oxide) + Nitrous oxide = (Iodide bullet 9Nitrous oxide)

By formula: (I- bullet 8N2O) + N2O = (I- bullet 9N2O)

Quantity Value Units Method Reference Comment
Deltar2.4 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(N2O2- bullet 4294967295Nitrous oxide) + Nitrous oxide = N2O2-

By formula: (N2O2- bullet 4294967295N2O) + N2O = N2O2-

Quantity Value Units Method Reference Comment
Deltar23.1 ± 1.2kcal/molN/ALi and Continetti, 2002gas phase; B
Deltar32.30 ± 0.70kcal/molLPDOsboen, Leahy, et al., 1996gas phase; Affinity at 0 K; B

(HO- bullet 3Nitrous oxide) + Nitrous oxide = (HO- bullet 4Nitrous oxide)

By formula: (HO- bullet 3N2O) + N2O = (HO- bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar>7. ± 33.kcal/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.981 eV. Affinity is EA difference with next lower +0.08 eV f; B

(HO- bullet 4Nitrous oxide) + Nitrous oxide = (HO- bullet 5Nitrous oxide)

By formula: (HO- bullet 4N2O) + N2O = (HO- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar>5. ± 54.kcal/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 3.146 eV. Affinity is EA difference with next lower +0.08 eV f; B

(HO- bullet 2Nitrous oxide) + Nitrous oxide = (HO- bullet 3Nitrous oxide)

By formula: (HO- bullet 2N2O) + N2O = (HO- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar6.90kcal/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.761 eV. Affinity is EA difference with next lower +0.08 eV f; B

(HO- bullet Nitrous oxide) + Nitrous oxide = (HO- bullet 2Nitrous oxide)

By formula: (HO- bullet N2O) + N2O = (HO- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar7.80kcal/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.485 eV. Affinity is EA difference with next lower +0.08 eV f; B

(Chlorine anion bullet 2Nitrous oxide) + Nitrous oxide = (Chlorine anion bullet 3Nitrous oxide)

By formula: (Cl- bullet 2N2O) + N2O = (Cl- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar5.1 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Chlorine anion bullet 3Nitrous oxide) + Nitrous oxide = (Chlorine anion bullet 4Nitrous oxide)

By formula: (Cl- bullet 3N2O) + N2O = (Cl- bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar4.9 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.9cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion bullet 2Nitrous oxide) + Nitrous oxide = (Fluorine anion bullet 3Nitrous oxide)

By formula: (F- bullet 2N2O) + N2O = (F- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar8.4 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.6cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S., Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O, J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524 . [all data]

Illies, 1988
Illies, A.J., Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures, J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037 . [all data]

Cameron, Aitken, et al., 1994
Cameron, B.R.; Aitken, C.G.; Harland, P.W., Appearence Energies of Small Cluster Ions and their Fragments, J. Chem. Soc. Faraday Trans., 1994, 90, 7, 935, https://doi.org/10.1039/ft9949000935 . [all data]

Linn and Ng, 1981
Linn, S.H.; Ng, C.Y., Photoionization Study of CO2, N2O Dimers and Clusters, J. Chem. Phys., 1981, 75, 10, 4921, https://doi.org/10.1063/1.441931 . [all data]

Adams and Bohme, 1970
Adams, N.G.; Bohme, D., Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-, J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

Hendricks, de Clercq, et al., 2002
Hendricks, J.H.; de Clercq, H.L.; Freidhoff, C.B.; Arnold, S.T.; Eaton, J.G.; Fancher, C.; Lyapustina, S.A.; S., Anion solvation at the microscopic level: Photoelectron spectroscopy of the solvated anion clusters, NO-(Y)(n), where Y=Ar, Kr, Xe, N2O, H2S, NH3, H2O, and C2H4(OH)(2), J. Chem. Phys., 2002, 116, 18, 7926-7938, https://doi.org/10.1063/1.1457444 . [all data]

Coe, Snodgrass, et al., 1987
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H., Photoelectron spectroscopy of the negative cluster ions, NO-(N2O)n=1,2, J. Chem. Phys., 1987, 87, 4302. [all data]

Hiraoka, Fujimaki, et al., 1994, 2
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Gas-phase clustering reactions of O2(-), NO-, and O- with N2O: Isomeric structures for (NO-N2O)(-), J. Phys. Chem., 1994, 98, 34, 8295, https://doi.org/10.1021/j100085a006 . [all data]

Coe, Snodgrass, et al., 1986
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H., Negative ion photoelectron spectroscopy of N2O- and (N2O)2-, Chem. Phys. Lett., 1986, 124, 274. [all data]

Szulejko and McMahon, 1992
Szulejko, J.; McMahon, T.B., personal communication, 1992. [all data]

McMahon, Heinis, et al., 1988
McMahon, T.; Heinis, T.; Nicol, G.; Hovey, J.K.; Kebarle, P., Methyl Cation Affinities, J. Am. Chem. Soc., 1988, 110, 23, 7591, https://doi.org/10.1021/ja00231a002 . [all data]

Foster, Williamson, et al., 1974
Foster, M.S.; Williamson, A.D.; Beauchamp, J.L., Photoionization mass spectrometry of trans-azomethane, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 429. [all data]

Li and Continetti, 2002
Li, R.J.; Continetti, R.E., Studies of the excited state dynamics of N2O2 by dissociative photodetachment of N2O2-, J. Phys. Chem. A, 2002, 106, 7, 1183-1189, https://doi.org/10.1021/jp013330u . [all data]

Osboen, Leahy, et al., 1996
Osboen, D.L.; Leahy, D.J.; Cyr, D.R.; Neumark, D.M., Photodissociation Spectroscopy and Dynamics of the N2O2- Anion, J. Chem. Phys., 1996, 104, 13, 5026, https://doi.org/10.1063/1.471132 . [all data]

Kim, Wenthold, et al., 1998
Kim, J.B.; Wenthold, P.G.; Lineberger, W.C., Photoelectron spectroscopy of OH-(N2O)(n=1-5), J. Chem. Phys., 1998, 108, 3, 830-837, https://doi.org/10.1063/1.475447 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References