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Nitrous oxide

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 83

(Fluorine anion bullet 3Nitrous oxide) + Nitrous oxide = (Fluorine anion bullet 4Nitrous oxide)

By formula: (F- bullet 3N2O) + N2O = (F- bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.4cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion bullet 4Nitrous oxide) + Nitrous oxide = (Fluorine anion bullet 5Nitrous oxide)

By formula: (F- bullet 4N2O) + N2O = (F- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar6.3 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.5cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion bullet 5Nitrous oxide) + Nitrous oxide = (Fluorine anion bullet 6Nitrous oxide)

By formula: (F- bullet 5N2O) + N2O = (F- bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar6.0 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.8cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Bromine anion bullet 2Nitrous oxide) + Nitrous oxide = (Bromine anion bullet 3Nitrous oxide)

By formula: (Br- bullet 2N2O) + N2O = (Br- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar5.0 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Chlorine anion bullet Nitrous oxide) + Nitrous oxide = (Chlorine anion bullet 2Nitrous oxide)

By formula: (Cl- bullet N2O) + N2O = (Cl- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar5.6 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.5cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion bullet Nitrous oxide) + Nitrous oxide = (Fluorine anion bullet 2Nitrous oxide)

By formula: (F- bullet N2O) + N2O = (F- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.7cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Bromine anion bullet Nitrous oxide) + Nitrous oxide = (Bromine anion bullet 2Nitrous oxide)

By formula: (Br- bullet N2O) + N2O = (Br- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar5.4 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(H- bullet 4294967295Nitrous oxide) + Nitrous oxide = H-

By formula: (H- bullet 4294967295N2O) + N2O = H-

Quantity Value Units Method Reference Comment
Deltar59.3 ± 4.1kcal/molTherSheldon, Ohair, et al., 1995gas phase; Acidity between PhCOMe, HCONHMe, near CF3CH2OH. Acid: H2N-NO; B

(Hydronium cation bullet 2Nitrous oxide) + Nitrous oxide = (Hydronium cation bullet 3Nitrous oxide)

By formula: (H3O+ bullet 2N2O) + N2O = (H3O+ bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar10.2kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation bullet 2Nitrous oxide) + Nitrous oxide = (Oxygen cation bullet 3Nitrous oxide)

By formula: (O2+ bullet 2N2O) + N2O = (O2+ bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar5.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation bullet 3Nitrous oxide) + Nitrous oxide = (Oxygen cation bullet 4Nitrous oxide)

By formula: (O2+ bullet 3N2O) + N2O = (O2+ bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar5.2kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation bullet 4Nitrous oxide) + Nitrous oxide = (Oxygen cation bullet 5Nitrous oxide)

By formula: (O2+ bullet 4N2O) + N2O = (O2+ bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar4.8kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation bullet 5Nitrous oxide) + Nitrous oxide = (Oxygen cation bullet 6Nitrous oxide)

By formula: (O2+ bullet 5N2O) + N2O = (O2+ bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar4.3kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation bullet 6Nitrous oxide) + Nitrous oxide = (Oxygen cation bullet 7Nitrous oxide)

By formula: (O2+ bullet 6N2O) + N2O = (O2+ bullet 7N2O)

Quantity Value Units Method Reference Comment
Deltar3.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Hydronium cation bullet Nitrous oxide) + Nitrous oxide = (Hydronium cation bullet 2Nitrous oxide)

By formula: (H3O+ bullet N2O) + N2O = (H3O+ bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar12.1kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ bullet 3Nitrous oxide) + Nitrous oxide = (NO2+ bullet 4Nitrous oxide)

By formula: (NO2+ bullet 3N2O) + N2O = (NO2+ bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar4.4kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ bullet 4Nitrous oxide) + Nitrous oxide = (NO2+ bullet 5Nitrous oxide)

By formula: (NO2+ bullet 4N2O) + N2O = (NO2+ bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar4.1kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation bullet Nitrous oxide) + Nitrous oxide = (Oxygen cation bullet 2Nitrous oxide)

By formula: (O2+ bullet N2O) + N2O = (O2+ bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar7.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ bullet 2Nitrous oxide) + Nitrous oxide = (HN2O+ bullet 3Nitrous oxide)

By formula: (HN2O+ bullet 2N2O) + N2O = (HN2O+ bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar5.8kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ bullet 3Nitrous oxide) + Nitrous oxide = (HN2O+ bullet 4Nitrous oxide)

By formula: (HN2O+ bullet 3N2O) + N2O = (HN2O+ bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar5.4kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ bullet 4Nitrous oxide) + Nitrous oxide = (HN2O+ bullet 5Nitrous oxide)

By formula: (HN2O+ bullet 4N2O) + N2O = (HN2O+ bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar5.0kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ bullet Nitrous oxide) + Nitrous oxide = (HN2O+ bullet 2Nitrous oxide)

By formula: (HN2O+ bullet N2O) + N2O = (HN2O+ bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar6.4kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

Chlorine anion + Nitrous oxide = (Chlorine anion bullet Nitrous oxide)

By formula: Cl- + N2O = (Cl- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar5.8 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.2cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Fluorine anion + Nitrous oxide = (Fluorine anion bullet Nitrous oxide)

By formula: F- + N2O = (F- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar9.9 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.9cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Bromine anion + Nitrous oxide = (Bromine anion bullet Nitrous oxide)

By formula: Br- + N2O = (Br- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar5.6 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.1cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Hydronium cation + Nitrous oxide = (Hydronium cation bullet Nitrous oxide)

By formula: H3O+ + N2O = (H3O+ bullet N2O)

Quantity Value Units Method Reference Comment
Deltar16.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

C5N2O6W (g) = C5O5W (g) + Nitrous oxide (g)

By formula: C5N2O6W (g) = C5O5W (g) + N2O (g)

Quantity Value Units Method Reference Comment
Deltar14.6 ± 0.50kcal/molKinGWeitz, 1994MS
Deltar22. ± 2.kcal/molESTBogdan, Wells, et al., 1991MS

C7H8N2O = Nitrous oxide + Norcaradiene

By formula: C7H8N2O = N2O + C7H8

Quantity Value Units Method Reference Comment
Deltar-16.38 ± 0.85kcal/molKinOth, Olsen, et al., 1977liquid phase; solvent: THF; At 337K; ALS

2,3-Diazabicyclo[2.2.2]octa-2,5-diene N-oxide = Nitrous oxide + 1,3-Cyclohexadiene

By formula: C6H8N2O = N2O + C6H8

Quantity Value Units Method Reference Comment
Deltar-0.84 ± 0.06kcal/molKinOth, Olsen, et al., 1977liquid phase; solvent: THF; At 452 K; ALS

C8H8N2O = Nitrous oxide + Bicyclo[4.2.0]octa-1,3,5-triene

By formula: C8H8N2O = N2O + C8H8

Quantity Value Units Method Reference Comment
Deltar-9.85 ± 0.13kcal/molKinOth, Olsen, et al., 1977liquid phase; solvent: THF; At 413 K; ALS

C9H12N2O = Nitrous oxide + Indan, 3a,7a-dihydro-

By formula: C9H12N2O = N2O + C9H12

Quantity Value Units Method Reference Comment
Deltar-0.71 ± 0.12kcal/molKinOth, Olsen, et al., 1977liquid phase; solvent: THF; ALS

C8H10N2O = Nitrous oxide + Bicyclo[4.2.0]octa-2,4-diene

By formula: C8H10N2O = N2O + C8H10

Quantity Value Units Method Reference Comment
Deltar-2.31 ± 0.09kcal/molKinOth, Olsen, et al., 1977gas phase; At 426 K; ALS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

Sheldon, Ohair, et al., 1995
Sheldon, J.C.; Ohair, R.A.J.; Downard, K.M.; Gronert, S.; Krempp, M.; Depuy, C.H.; Bowie, J.H., A potential surface map of the H-/N2O system. The gas phase ion chemistry of HN2O-, Aust. J. Chem., 1995, 48, 155. [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S., Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O, J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524 . [all data]

Weitz, 1994
Weitz, E., J. Phys. Chem., 1994, 98, 11256. [all data]

Bogdan, Wells, et al., 1991
Bogdan, P.L.; Wells, J.R.; Weitz, E., J. Am. Chem. Soc., 1991, 113, 1294. [all data]

Oth, Olsen, et al., 1977
Oth, J.F.M.; Olsen, H.; Synder, J.P., Energetics of heteroextrusion reactions. N2 vs. N2O, J. Am. Chem. Soc., 1977, 99, 8505-8507. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References