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Molybdenum tetrakis(dimethylamide)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas31.4 ± 1.9kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid14.1 ± 1.2kcal/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub17. ± 1.kcal/molCAdedeji, Cavell, et al., 1979See also Pilcher and Skinner, 1983.; AC
Deltasub17.3 ± 1.4kcal/molRSCAdedeji, Cavell, et al., 1979MS

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
21.1 ± 0.7376.CAdedeji, Cavell, et al., 1979AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
5.30PEChisholm, Cowley, et al., 1980Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Adedeji, Cavell, et al., 1979
Adedeji, F.A.; Cavell, K.J.; Cavell, S.; Connor, J.A.; Skinner, H.A.; Zafarani-Moattar, M.T., J. Chem. Soc. Faraday Trans. 1, 1979, 75, 603. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Chisholm, Cowley, et al., 1980
Chisholm, M.H.; Cowley, A.H.; Lattman, M., A UV photoelectron spectroscopic investigation of the bonding in some tri-, tetra-, and penta- coordinated dialkylamino compounds of chromium, molybdenum, niobium, and tantalum, J. Am. Chem. Soc., 1980, 102, 46. [all data]


Notes

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