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1-Tert-butoxybutane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil397.15KN/ACampbell, Burney, et al., 1950Uncertainty assigned by TRC = 4. K; TRC
Tboil397.KN/ANorris and Rigby, 1932Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Deltavap43.2kJ/molN/AVerevkin, Krasnykh, et al., 2003See also Verevkin, 2002.; AC
Deltavap41.6 ± 0.2kJ/molCVarushchenko, Aitkeeva, et al., 2002AC
Deltavap42.3 ± 0.3kJ/molCSharonov, Mishentseva, et al., 1991AC
Deltavap42.33 ± 0.25kJ/molCSharonov, Mishentseva, et al., 1991, 2ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
41.7308.AStephenson and Malanowski, 1987Based on data from 293. - 397. K.; AC
38.3371.EBStephenson and Malanowski, 1987Based on data from 356. - 397. K. See also Sheehan and Langer, 1969.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Campbell, Burney, et al., 1950
Campbell, T.W.; Burney, W.; Jacobs, T.L., THe Reaction of Gignard Reagents with D-t-butyl Peroxide, J. Am. Chem. Soc., 1950, 72, 2735. [all data]

Norris and Rigby, 1932
Norris, J.F.; Rigby, G.W., Reactivity of Atoms and Groups in Organic Compounds XII. The Preparation and Properties of Mixed Aliphatic Ethers with Special Reference to those Containing the Tert-Butyl Radical, J. Am. Chem. Soc., 1932, 54, 2088. [all data]

Verevkin, Krasnykh, et al., 2003
Verevkin, Sergey P.; Krasnykh, Eugen L.; Vasiltsova, Tatiana V.; Heintz, Andreas, Determination of Ambient Temperature Vapor Pressures and Vaporization Enthalpies of Branched Ethers, J. Chem. Eng. Data, 2003, 48, 3, 591-599, https://doi.org/10.1021/je0255980 . [all data]

Verevkin, 2002
Verevkin, Sergey P., Improved Benson Increments for the Estimation of Standard Enthalpies of Formation and Enthalpies of Vaporization of Alkyl Ethers, Acetals, Ketals, and Ortho Esters, J. Chem. Eng. Data, 2002, 47, 5, 1071-1097, https://doi.org/10.1021/je020023o . [all data]

Varushchenko, Aitkeeva, et al., 2002
Varushchenko, R.M.; Aitkeeva, Ch.A.; Druzhinina, A.I.; Myshentseva, Yu.A.; Pashchenko, L.L., Zh. Fiz. Khim., 2002, 76, 5, 824. [all data]

Sharonov, Mishentseva, et al., 1991
Sharonov, K.G.; Mishentseva, Y.B.; Rozhnov, A.M.; Miroshnichenko, E.A.; Korchatova, L.I., Molar enthalpies of formation and vaporization of t-butoxybutanes and thermodynamics of their synthesis from a butanol and 2-methylpropene, The Journal of Chemical Thermodynamics, 1991, 23, 7, 636-642, https://doi.org/10.1016/S0021-9614(05)80200-9 . [all data]

Sharonov, Mishentseva, et al., 1991, 2
Sharonov, K.G.; Mishentseva, Y.B.; Rozhnov, A.M.; Miroshnichenko, E.A.; Korchatova, L.I., Molar enthalpies of formation and vaporization of t-butoxybutanes and thermodynamics of their synthesis from a butanol and 2-methylpropene 2. Enthalpies of combustion and vaporization of t-butoxybutanes, J. Chem. Thermodyn., 1991, 23, 637-642. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Sheehan and Langer, 1969
Sheehan, Richard J.; Langer, Stanley H., Vapor pressures of fluorine- and silicon-containing derivatives of some hydroxylic compounds, J. Chem. Eng. Data, 1969, 14, 2, 248-250, https://doi.org/10.1021/je60041a011 . [all data]


Notes

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