1-Tert-butoxybutane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-361.0 ± 1.9kJ/molCcbSharonov, Mishentseva, et al., 1991 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-403.3 ± 1.9kJ/molCcbSharonov, Mishentseva, et al., 1991 
Quantity Value Units Method Reference Comment
Δcliquid-5317.3 ± 1.5kJ/molCcbSharonov, Mishentseva, et al., 1991Corresponding Δfliquid = -403.3 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil397.15KN/ACampbell, Burney, et al., 1950Uncertainty assigned by TRC = 4. K; TRC
Tboil397.KN/ANorris and Rigby, 1932Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δvap43.2kJ/molN/AVerevkin, Krasnykh, et al., 2003See also Verevkin, 2002.; AC
Δvap41.6 ± 0.2kJ/molCVarushchenko, Aitkeeva, et al., 2002AC
Δvap42.3 ± 0.3kJ/molCSharonov, Mishentseva, et al., 1991, 2AC
Δvap42.33 ± 0.25kJ/molCSharonov, Mishentseva, et al., 1991ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
41.7308.AStephenson and Malanowski, 1987Based on data from 293. to 397. K.; AC
38.3371.EBStephenson and Malanowski, 1987Based on data from 356. to 397. K. See also Sheehan and Langer, 1969.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1-Propene, 2-methyl- + 1-Butanol = 1-Tert-butoxybutane

By formula: C4H8 + C4H10O = C8H18O

Quantity Value Units Method Reference Comment
Δr-34.8 ± 2.7kJ/molEqkSharonov, Mishentseva, et al., 1991, 3liquid phase

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryMethyl Silicone100.796.2Boneva and Toromanova-Petrova, 1994Column length: 50. m; Column diameter: 0.25 mm
CapillaryMethyl Silicone90.796.0Boneva and Toromanova-Petrova, 1994Column length: 50. m; Column diameter: 0.25 mm

Normal alkane RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryDB-560.803.Verevkin, Krasnykh, et al., 200360. m/0.32 mm/0.25 μm, Nitrogen

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sharonov, Mishentseva, et al., 1991
Sharonov, K.G.; Mishentseva, Y.B.; Rozhnov, A.M.; Miroshnichenko, E.A.; Korchatova, L.I., Molar enthalpies of formation and vaporization of t-butoxybutanes and thermodynamics of their synthesis from a butanol and 2-methylpropene 2. Enthalpies of combustion and vaporization of t-butoxybutanes, J. Chem. Thermodyn., 1991, 23, 637-642. [all data]

Campbell, Burney, et al., 1950
Campbell, T.W.; Burney, W.; Jacobs, T.L., THe Reaction of Gignard Reagents with D-t-butyl Peroxide, J. Am. Chem. Soc., 1950, 72, 2735. [all data]

Norris and Rigby, 1932
Norris, J.F.; Rigby, G.W., Reactivity of Atoms and Groups in Organic Compounds XII. The Preparation and Properties of Mixed Aliphatic Ethers with Special Reference to those Containing the Tert-Butyl Radical, J. Am. Chem. Soc., 1932, 54, 2088. [all data]

Verevkin, Krasnykh, et al., 2003
Verevkin, Sergey P.; Krasnykh, Eugen L.; Vasiltsova, Tatiana V.; Heintz, Andreas, Determination of Ambient Temperature Vapor Pressures and Vaporization Enthalpies of Branched Ethers, J. Chem. Eng. Data, 2003, 48, 3, 591-599, https://doi.org/10.1021/je0255980 . [all data]

Verevkin, 2002
Verevkin, Sergey P., Improved Benson Increments for the Estimation of Standard Enthalpies of Formation and Enthalpies of Vaporization of Alkyl Ethers, Acetals, Ketals, and Ortho Esters, J. Chem. Eng. Data, 2002, 47, 5, 1071-1097, https://doi.org/10.1021/je020023o . [all data]

Varushchenko, Aitkeeva, et al., 2002
Varushchenko, R.M.; Aitkeeva, Ch.A.; Druzhinina, A.I.; Myshentseva, Yu.A.; Pashchenko, L.L., Zh. Fiz. Khim., 2002, 76, 5, 824. [all data]

Sharonov, Mishentseva, et al., 1991, 2
Sharonov, K.G.; Mishentseva, Y.B.; Rozhnov, A.M.; Miroshnichenko, E.A.; Korchatova, L.I., Molar enthalpies of formation and vaporization of t-butoxybutanes and thermodynamics of their synthesis from a butanol and 2-methylpropene, The Journal of Chemical Thermodynamics, 1991, 23, 7, 636-642, https://doi.org/10.1016/S0021-9614(05)80200-9 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Sheehan and Langer, 1969
Sheehan, Richard J.; Langer, Stanley H., Vapor pressures of fluorine- and silicon-containing derivatives of some hydroxylic compounds, J. Chem. Eng. Data, 1969, 14, 2, 248-250, https://doi.org/10.1021/je60041a011 . [all data]

Sharonov, Mishentseva, et al., 1991, 3
Sharonov, K.G.; Mishentseva, Y.B.; Rozhnov, A.M.; Miroshnichenko, E.A.; Korchatova, L.I., Molar enthalpies of formation and vaporizqation of t-butoxybutanes and thermodynamics of their synthesis from a butanol and 2-methylpropene I. Equilibria of synthesis reactions of t-butoxybutanes in the liquid phase, J. Chem. Thermodyn., 1991, 23, 141-145. [all data]

Boneva and Toromanova-Petrova, 1994
Boneva, S.; Toromanova-Petrova, P., Capillary gas chromatography of C1-C4 alkyl tert-butyl ethers, Chromatographia, 1994, 39, 3/4, 224-227, https://doi.org/10.1007/BF02274504 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas Chromatography, References