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Phenol, 4-nitro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-207.1 ± 1.1kJ/molCcrSabbah and Gouali, 1994Author was aware that data differs from previously reported values; ALS
Deltafsolid-212.4 ± 1.0kJ/molCcbFinch, Gardner, et al., 1983ALS
Deltafsolid-226.7kJ/molCcbRinkenbach, 1930Author hf298_condensed[kcal/mol]=-56.50; ALS
Deltafsolid-209.kJ/molCcbSwarts, 1914See 14SWA2; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-2868.5 ± 1.0kJ/molCcrSabbah and Gouali, 1994Author was aware that data differs from previously reported values; ALS
Deltacsolid-2863.21 ± 0.54kJ/molCcbFinch, Gardner, et al., 1983ALS
Deltacsolid-2848.9kJ/molCcbRinkenbach, 1930Author hf298_condensed[kcal/mol]=-56.50; ALS
Deltacsolid-2874.kJ/molCcbGarner and Abernethy, 1921ALS
Deltacsolid-2879.6kJ/molCcbSwarts, 1914See 14SWA2; ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
144.283.Campbell and Campbell, 1941T = 273 to 293 K. Value given as Cp = 0.248 cal/g over temperature range 0 to 20°C.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sabbah and Gouali, 1994
Sabbah, R.; Gouali, M., Energetics of intra- and inter-molecular bonds in the three nitrophenols, Aust. J. Chem., 1994, 47, 1651-1660. [all data]

Finch, Gardner, et al., 1983
Finch, A.; Gardner, P.J.; Wu, D., Studies on nitrophenols. Part IV. The standard enthalpies of combustion and formation of 1,2-dihydroxybenzene, 1,2- and 1,4-nitrophenol, Thermochim. Acta, 1983, 66, 333-342. [all data]

Rinkenbach, 1930
Rinkenbach, W.H., The heats of combustion and formation of aromatic nitro compounds, J. Am. Chem. Soc., 1930, 52, 115-120. [all data]

Swarts, 1914
Swarts, F., Sur la chaleur de combustion de quelques derives nitres aromatlques, Recl. Trav. Chim. Pays-Bas, 1914, 33, 281-298. [all data]

Garner and Abernethy, 1921
Garner, W.E.; Abernethy, C.L., Heats of combustion and formation of nitro-compounds. Part I. - Benzene, toluene, phenol and methylaniline series, Proc. Roy. Soc. London A, 1921, 213-235. [all data]

Campbell and Campbell, 1941
Campbell, A.N.; Campbell, A.J.R., The system naphthalene-p-nitrophenol: an experimental investigation of all the variables in an equation of the freezing point curve, Can. J. Res., 1941, B19, 73-79. [all data]


Notes

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