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p-Nitroaniline

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-45.6 ± 1.2kJ/molCcrNishiyama, Sakiyama, et al., 1983ALS
Deltafsolid-43.1 ± 0.8kJ/molCcbLebedeva, Gutner, et al., 1971Hfusion=5.1±0.2, see Lebedeva, Rjadnenko, et al., 1969; ALS
Deltafsolid-38.5 ± 3.2kJ/molCcbMedard and Thomas, 1954Heat of combustion corrected for pressure; ALS
Deltafsolid-41.5kJ/molCmCole and Gilbert, 1951ALS
Quantity Value Units Method Reference Comment
Deltacsolid-3172.98 ± 0.90kJ/molCcrNishiyama, Sakiyama, et al., 1983ALS
Deltacsolid-3176. ± 0.8kJ/molCcbLebedeva, Gutner, et al., 1971Hfusion=5.1±0.2, see Lebedeva, Rjadnenko, et al., 1969; ALS
Deltacsolid-3180.0 ± 3.2kJ/molCcbMedard and Thomas, 1954Heat of combustion corrected for pressure; ALS
Deltacsolid-3177.1kJ/molCmCole and Gilbert, 1951ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
154.2298.15Nishiyama, Sakiyama, et al., 1983Cp given as 1.116 J/g*K.; DH
184.9323.Satoh and Sogabe, 1941T = 0 to 100°C. Mean value.; DH
169.0298.Andrews, Lynn, et al., 1926T = 22 to 195°C.; DH
165.7297.9Andrews, 1926T = 110 to 344 K. Value is unsmoothed experimental datum.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nishiyama, Sakiyama, et al., 1983
Nishiyama, K.; Sakiyama, M.; Seki, S., Enthalpies of combustion of organic compounds. V. 3- and 4-nitroanilines, Bull. Chem. Soc. Jpn., 1983, 56, 3171-3172. [all data]

Lebedeva, Gutner, et al., 1971
Lebedeva, N.D.; Gutner, N.M.; Ryadnenko, V.L., Heats of combustion and formation of certain aromatic amino-derivatives, Russ. J. Phys. Chem. (Engl. Transl.), 1971, 45, 561-562. [all data]

Lebedeva, Rjadnenko, et al., 1969
Lebedeva, N.D.; Rjadnenko, B.L.; Gutner, N.M., Heats of formation of some N-containing organic compounds, Int. Conf. Calorim. Therm. (Warsaw, Poland), 1969, 1-8. [all data]

Medard and Thomas, 1954
Medard, L.; Thomas, M., Chaleurs de combustion de vingt-quatre substances explosives ou apparentees a des explosifs, Mem. Poudres, 1954, 36, 97-127. [all data]

Cole and Gilbert, 1951
Cole, L.G.; Gilbert, E.C., The heats of combustion of some nitrogen compounds and the apparent energy of the N-N bond, J. Am. Chem. Soc., 1951, 73, 5423-5427. [all data]

Satoh and Sogabe, 1941
Satoh, S.; Sogabe, T., The heat capacities of some organic compounds containing nitrogen and the atomic heat of nitrogen. (3), Sci., Pap. Inst. Phys. Chem. Res. (Tokyo), 1941, 38, 238-245. [all data]

Andrews, Lynn, et al., 1926
Andrews, D.H.; Lynn, G.; Johnston, J., The heat capacities and heat of crystallization of some isomeric aromatic compounds, J. Am. Chem. Soc., 1926, 48, 1274-1287. [all data]

Andrews, 1926
Andrews, D.H., The specific heats of some isomers of the type ortho, meta and para C6H4XY from 110 to 340K, J. Am. Chem. Soc., 1926, 48, 1287-1298. [all data]


Notes

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