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FCO2 anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
4.277 ± 0.030LPESArnold, Bradforth, et al., 1995 

Protonation reactions

CFO2- + Hydrogen cation = CHFO2

By formula: CFO2- + H+ = CHFO2

Quantity Value Units Method Reference Comment
Deltar1380. ± 33.kJ/molD-EAArnold, Bradforth, et al., 1995gas phase
Deltar1374.4kJ/molAcidLarson and McMahon, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar1350. ± 33.kJ/molH-TSArnold, Bradforth, et al., 1995gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of halogen carbon dioxide clusters and the fluoroformyloxyl radical by photodetachment of X(-)(CO2) (X=I,Cl,Br) and FCO2-, J. Chem. Phys., 1995, 102, 9, 3493, https://doi.org/10.1063/1.468575 . [all data]

Larson and McMahon, 1985
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of the main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ICR halide exchange equilibria, J. Am. Chem. Soc., 1985, 107, 766. [all data]


Notes

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