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FCO2 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-183.8 ± 9.3kcal/molAcidArnold, Bradforth, et al., 1995 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CFO2- + Hydrogen cation = CHFO2

By formula: CFO2- + H+ = CHFO2

Quantity Value Units Method Reference Comment
Deltar329.9 ± 7.8kcal/molD-EAArnold, Bradforth, et al., 1995gas phase
Deltar328.49kcal/molAcidLarson and McMahon, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar322.6 ± 7.9kcal/molH-TSArnold, Bradforth, et al., 1995gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of halogen carbon dioxide clusters and the fluoroformyloxyl radical by photodetachment of X(-)(CO2) (X=I,Cl,Br) and FCO2-, J. Chem. Phys., 1995, 102, 9, 3493, https://doi.org/10.1063/1.468575 . [all data]

Larson and McMahon, 1985
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of the main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ICR halide exchange equilibria, J. Am. Chem. Soc., 1985, 107, 766. [all data]


Notes

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