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CH2=NO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH2NO- + Hydrogen cation = formaldehyde oxime

By formula: CH2NO- + H+ = CH3NO

Quantity Value Units Method Reference Comment
Deltar<1557.3kJ/molAcidDiDomenico and Franklin, 1972gas phase; From MeNO2. G3MP2B3 calculations indicate a HOF(A-) of +3 kcal/mol

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CH2NO- + Hydrogen cation = formaldehyde oxime

By formula: CH2NO- + H+ = CH3NO

Quantity Value Units Method Reference Comment
Deltar<1557.3kJ/molAcidDiDomenico and Franklin, 1972gas phase; From MeNO2. G3MP2B3 calculations indicate a HOF(A-) of +3 kcal/mol

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DiDomenico and Franklin, 1972
DiDomenico, A.; Franklin, J.L., Negative ions in the mass spectrum of nitromethane, Int. J. Mass Spectrom. Ion Phys., 1972, 9, 171. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References