H2O..HO anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-117.77kcal/molTherPaul and Kebarle, 1990 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.95 ± 0.15PDGolub and Steiner, 1968For a complete Fragment KE/LPES analysis, see Deyerl, Luong, et al., 2000

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Thermodynamics of the Association Reactions OH- - H2O = HOHOH- and CH3O- - CH3OH = CH3OHOCH3- in the Gas Phase, J. Phys. Chem., 1990, 94, 12, 5184, https://doi.org/10.1021/j100375a076 . [all data]

Golub and Steiner, 1968
Golub, S.; Steiner, B., Photodetachment of {OH(H2O)}-, J. Chem. Phys., 1968, 49, 11, 5191, https://doi.org/10.1063/1.1670021 . [all data]

Deyerl, Luong, et al., 2000
Deyerl, H.J.; Luong, A.K.; Clements, T.G.; Continetti, R.E., Transition state dynamics of the OH+H2O hydrogen exchange reaction studied by dissociative photodetachment of H3O2-, Faraday Disc. Chem. Soc., 2000, 115, 147-160, https://doi.org/10.1039/a909619a . [all data]


Notes

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