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C2F5 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2F5- + Hydrogen cation = Ethane, pentafluoro-

By formula: C2F5- + H+ = C2HF5

Quantity Value Units Method Reference Comment
Deltar374.5 ± 3.3kcal/molG+TSSullivan and Beauchamp, 1976gas phase; Between tBuOH and HF; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar366.8 ± 3.2kcal/molIMRBSullivan and Beauchamp, 1976gas phase; Between tBuOH and HF; value altered from reference due to change in acidity scale

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sullivan and Beauchamp, 1976
Sullivan, S.A.; Beauchamp, J.L., Competition between proton transfer and elimination in the reactions of strong bases with fluoroethanes in the gas phase. Influence of base strength on reactivity, J. Am. Chem. Soc., 1976, 98, 1160. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References