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MeSCH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H5S- + Hydrogen cation = Dimethyl sulfide

By formula: C2H5S- + H+ = C2H6S

Quantity Value Units Method Reference Comment
Deltar1633. ± 6.3kJ/molD-EAMoran and Ellison, 1988gas phase
Deltar1645. ± 8.8kJ/molG+TSIngemann and Nibbering, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar1602. ± 7.1kJ/molH-TSMoran and Ellison, 1988gas phase
Deltar1615. ± 8.4kJ/molIMREIngemann and Nibbering, 1985gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Moran and Ellison, 1988
Moran, S.; Ellison, G.B., Photoelectron Spectroscopy of Sulfur Ions, J. Phys. Chem., 1988, 92, 7, 1794, https://doi.org/10.1021/j100318a021 . [all data]

Ingemann and Nibbering, 1985
Ingemann, S.; Nibbering, N.M.M., Gas phase chemistry of alpha-thio carbanions, Can. J. Chem., 1985, 62, 2273. [all data]


Notes

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