MeCH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H5- + Hydrogen cation = Ethane

By formula: C2H5- + H+ = C2H6

Quantity Value Units Method Reference Comment
Δr420.1 ± 2.0kcal/molBranDePuy, Gronert, et al., 1989gas phase
Δr421.0 ± 2.0kcal/molBranDePuy, Bierbaum, et al., 1984gas phase
Quantity Value Units Method Reference Comment
Δr411.7 ± 2.1kcal/molH-TSDePuy, Gronert, et al., 1989gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C2H5- + Hydrogen cation = Ethane

By formula: C2H5- + H+ = C2H6

Quantity Value Units Method Reference Comment
Δr420.1 ± 2.0kcal/molBranDePuy, Gronert, et al., 1989gas phase
Δr421.0 ± 2.0kcal/molBranDePuy, Bierbaum, et al., 1984gas phase
Quantity Value Units Method Reference Comment
Δr411.7 ± 2.1kcal/molH-TSDePuy, Gronert, et al., 1989gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy, Gronert, et al., 1989
DePuy, C.H.; Gronert, S.; Barlow, S.E.; Bierbaum, V.M.; Damrauer, R., The Gas Phase Acidities of the Alkanes, J. Am. Chem. Soc., 1989, 111, 6, 1968, https://doi.org/10.1021/ja00188a003 . [all data]

DePuy, Bierbaum, et al., 1984
DePuy, C.H.; Bierbaum, V.M.; Damrauer, R., Relative Gas-Phase Acidities of the Alkanes, J. Am. Chem. Soc., 1984, 106, 4051. [all data]


Notes

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