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C2F3 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2F3- + Hydrogen cation = Ethene, trifluoro-

By formula: C2F3- + H+ = C2HF3

Quantity Value Units Method Reference Comment
Deltar1630. ± 24.kJ/molD-EASpyrou, Sauers, et al., 1983gas phase; From C3F8. G3MP2B3 calculations indicate an EA of ca. 2.4 eV, and HOF(A-) of -110 kcal/mol.

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C2F3- + Hydrogen cation = Ethene, trifluoro-

By formula: C2F3- + H+ = C2HF3

Quantity Value Units Method Reference Comment
Deltar1630. ± 24.kJ/molD-EASpyrou, Sauers, et al., 1983gas phase; From C3F8. G3MP2B3 calculations indicate an EA of ca. 2.4 eV, and HOF(A-) of -110 kcal/mol.

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Spyrou, Sauers, et al., 1983
Spyrou, S.M.; Sauers, I.; Christophorou, L.G., Electron attachment to the perfluoroalkanes n-CnF2n+2 (n = 1-6) and i-C4F10, J. Chem. Phys., 1983, 78, 7200. [all data]


Notes

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