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phenalenide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C13H9- + Hydrogen cation = 1H-Phenalene

By formula: C13H9- + H+ = C13H10

Quantity Value Units Method Reference Comment
Deltar350.9 ± 3.8kcal/molD-EAGygax, Peters, et al., 1979gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993
Quantity Value Units Method Reference Comment
Deltar344.2 ± 3.9kcal/molH-TSGygax, Peters, et al., 1979gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.07 ± 0.10PDGygax, Peters, et al., 1979BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993

Protonation reactions

C13H9- + Hydrogen cation = 1H-Phenalene

By formula: C13H9- + H+ = C13H10

Quantity Value Units Method Reference Comment
Deltar350.9 ± 3.8kcal/molD-EAGygax, Peters, et al., 1979gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993
Quantity Value Units Method Reference Comment
Deltar344.2 ± 3.9kcal/molH-TSGygax, Peters, et al., 1979gas phase; BDE: 65±2 kcal/mol, Gerst and Rüchardt, 1993

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gygax, Peters, et al., 1979
Gygax, R.; Peters, H.L.; Brauman, J.I., Photodetachment of electrons from anions of high symmetry. Electron photodetachment spectra of the cycloctatetraenyl and perinaphthenyl anions, J. Am. Chem. Soc., 1979, 101, 2567. [all data]

Gerst and Rüchardt, 1993
Gerst, M.; Rüchardt, C., H-Transferreaktionen mit Phenalen, Chem. Ber., 1993, 126, 4, 1039, https://doi.org/10.1002/cber.19931260426 . [all data]


Notes

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