CH2=C(CN)O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H2NO- + Hydrogen cation = Acetyl cyanide

By formula: C3H2NO- + H+ = C3H3NO

Quantity Value Units Method Reference Comment
Δr1441. ± 8.8kJ/molG+TSTaft, 1987gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr1413. ± 8.4kJ/molIMRETaft, 1987gas phase; value altered from reference due to change in acidity scale
Δr1432. ± 21.kJ/molIMRBBrauman and Blair, 1968gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft, 1987
Taft, R.W., The Nature and Analysis of Substitutent Electronic Effects, Personal communication. See also Prog. Phys. Org. Chem., 1987, 16, 1. [all data]

Brauman and Blair, 1968
Brauman, J.I.; Blair, L.K., Gas Phase Acidities of Carbon Acids, J. Am. Chem. Soc., 1968, 90, 20, 5636, https://doi.org/10.1021/ja01022a073 . [all data]


Notes

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