Me2C=C(iPr)O anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.466 ± 0.052PDZimmerman, Reed, et al., 1977 

Protonation reactions

C7H13O- + Hydrogen cation = 3-Pentanone, 2,4-dimethyl-

By formula: C7H13O- + H+ = C7H14O

Quantity Value Units Method Reference Comment
Δr1526. ± 9.6kJ/molD-EAZimmerman, Reed, et al., 1977gas phase
Quantity Value Units Method Reference Comment
Δr1496. ± 11.kJ/molH-TSZimmerman, Reed, et al., 1977gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zimmerman, Reed, et al., 1977
Zimmerman, A.H.; Reed, K.J.; Brauman, J.I., Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicals, J. Am. Chem. Soc., 1977, 99, 7203. [all data]


Notes

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