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EtCH=C(nPr)O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C7H13O- + Hydrogen cation = 4-Heptanone

By formula: C7H13O- + H+ = C7H14O

Quantity Value Units Method Reference Comment
Deltar1518. ± 10.kJ/molD-EAZimmerman, Reed, et al., 1977gas phase
Quantity Value Units Method Reference Comment
Deltar1488. ± 11.kJ/molH-TSZimmerman, Reed, et al., 1977gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.722 ± 0.056PDZimmerman, Reed, et al., 1977 

Protonation reactions

C7H13O- + Hydrogen cation = 4-Heptanone

By formula: C7H13O- + H+ = C7H14O

Quantity Value Units Method Reference Comment
Deltar1518. ± 10.kJ/molD-EAZimmerman, Reed, et al., 1977gas phase
Quantity Value Units Method Reference Comment
Deltar1488. ± 11.kJ/molH-TSZimmerman, Reed, et al., 1977gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zimmerman, Reed, et al., 1977
Zimmerman, A.H.; Reed, K.J.; Brauman, J.I., Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicals, J. Am. Chem. Soc., 1977, 99, 7203. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References