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cyclohexanone enolate anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C6H9O- + Hydrogen cation = Cyclohexanone

By formula: C6H9O- + H+ = C6H10O

Quantity Value Units Method Reference Comment
Deltar366.4 ± 2.0kcal/molD-EABrinkman, Berger, et al., 1993gas phase
Deltar365.8 ± 2.3kcal/molD-EAZimmerman, Jackson, et al., 1978gas phase
Deltar369.0 ± 4.2kcal/molG+TSBrickhouse and Squires, 1988gas phase; Between acetone, Me2C=NOH
Quantity Value Units Method Reference Comment
Deltar358.7 ± 2.3kcal/molH-TSBrinkman, Berger, et al., 1993gas phase
Deltar358.0 ± 2.6kcal/molH-TSZimmerman, Jackson, et al., 1978gas phase
Deltar361.2 ± 4.0kcal/molIMRBBrickhouse and Squires, 1988gas phase; Between acetone, Me2C=NOH

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brinkman, Berger, et al., 1993
Brinkman, E.A.; Berger, S.; Marks, J.; Brauman, J.I., Molecular Rotation and the Observation of Dipole-Bound States of Anions, J. Chem. Phys., 1993, 99, 10, 7586, https://doi.org/10.1063/1.465688 . [all data]

Zimmerman, Jackson, et al., 1978
Zimmerman, A.H.; Jackson, R.L.; Janousek, B.K.; Brauman, J.J., Electron photodetachment from cyclic enolate anions in the gas phase: Electron affinities of cyclic enolate radicals, J. Am. Chem. Soc., 1978, 100, 4674. [all data]

Brickhouse and Squires, 1988
Brickhouse, M.D.; Squires, R.R., Gas Phase Bronsted vs. Lewis Acid-Base Reactions of 6,6-Dimethylfulvene. A Sensitive Probe of the Electronic Structures of Organic Anions, J. Am. Chem. Soc., 1988, 110, 9, 2706, https://doi.org/10.1021/ja00217a002 . [all data]


Notes

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