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EtCH=CHO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C4H7O- + Hydrogen cation = Butanal

By formula: C4H7O- + H+ = C4H8O

Quantity Value Units Method Reference Comment
Deltar364.8 ± 2.1kcal/molD-EAAlconcel, Deyerl, et al., 2001gas phase
Deltar364.1 ± 2.3kcal/molD-EAZimmerman, Reed, et al., 1977gas phase
Quantity Value Units Method Reference Comment
Deltar358.2 ± 2.3kcal/molH-TSAlconcel, Deyerl, et al., 2001gas phase
Deltar357.6 ± 2.5kcal/molH-TSZimmerman, Reed, et al., 1977gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Alconcel, Deyerl, et al., 2001
Alconcel, L.S.; Deyerl, H.J.; Continetti, R.E., Effects of alkyl substitution on the energetics of enolate anions and radicals, J. Am. Chem. Soc., 2001, 123, 50, 12675-12681, https://doi.org/10.1021/ja0120431 . [all data]

Zimmerman, Reed, et al., 1977
Zimmerman, A.H.; Reed, K.J.; Brauman, J.I., Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicals, J. Am. Chem. Soc., 1977, 99, 7203. [all data]


Notes

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