CF3CF=CF2..Br anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Bromine anion + Propene, hexafluoro- = C3BrF6-

By formula: Br- + C3F6 = C3BrF6-

Quantity Value Units Method Reference Comment
Δr41.4 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase
Quantity Value Units Method Reference Comment
Δr17.7 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase

C3BrF6- + 2Propene, hexafluoro- = C6BrF12-

By formula: C3BrF6- + 2C3F6 = C6BrF12-

Quantity Value Units Method Reference Comment
Δr34.7 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase
Quantity Value Units Method Reference Comment
Δr7.3 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Bromine anion + Propene, hexafluoro- = C3BrF6-

By formula: Br- + C3F6 = C3BrF6-

Quantity Value Units Method Reference Comment
Δr41.4 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase
Quantity Value Units Method Reference Comment
Δr17.7 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase

C3BrF6- + 2Propene, hexafluoro- = C6BrF12-

By formula: C3BrF6- + 2C3F6 = C6BrF12-

Quantity Value Units Method Reference Comment
Δr34.7 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase
Quantity Value Units Method Reference Comment
Δr7.3 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Takao, et al., 2002
Hiraoka, K.; Takao, K.; Lino, T.; Nakagawa, F.; Suyama, H.; Mizuno, T.; Yamabe, S., Gas-phase ion-molecule reactions in C3F6, J. Phys. Chem. A, 2002, 106, 4, 603-611, https://doi.org/10.1021/jp0116306 . [all data]


Notes

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