CF3Br..Br anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-220.03 ± 0.56kcal/molTherBogdanov and McMahon, 2006 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Bromine anion + Bromotrifluoromethane = CBr2F3-

By formula: Br- + CBrF3 = CBr2F3-

Quantity Value Units Method Reference Comment
Δr13.90 ± 0.20kcal/molTDAsBogdanov and McMahon, 2006gas phase
Quantity Value Units Method Reference Comment
Δr7.28kcal/molTDAsBogdanov and McMahon, 2006gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bogdanov and McMahon, 2006
Bogdanov, B.; McMahon, T.B., Gas phase S(N)2 reactions of halide ions with trifluoromethyl halides: Front- and back-side attack vs. complex formation, J. Phys. Chem. A, 2006, 110, 4, 1350-1363, https://doi.org/10.1021/jp0541011 . [all data]


Notes

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