SiH radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas246. ± 11.kJ/molAcidKasdan, Herbst, et al., 1975 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

HSi- + Hydrogen cation = Silylene

By formula: HSi- + H+ = H2Si

Quantity Value Units Method Reference Comment
Δr1502. ± 9.6kJ/molD-EAKasdan, Herbst, et al., 1975gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

HSi- + Hydrogen cation = Silylene

By formula: HSi- + H+ = H2Si

Quantity Value Units Method Reference Comment
Δr1502. ± 9.6kJ/molD-EAKasdan, Herbst, et al., 1975gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kasdan, Herbst, et al., 1975
Kasdan, A.; Herbst, E.; Lineberger, W.C., Laser photoelectron spectrometry of the negative ions of silicon and its hydrides, J. Chem. Phys., 1975, 62, 541. [all data]


Notes

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