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3-Me-bicyclo[1.1.1]pentane-1-CO2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C7H9O2- + Hydrogen cation = C7H10O2

By formula: C7H9O2- + H+ = C7H10O2

Quantity Value Units Method Reference Comment
Deltar344.5 ± 2.1kcal/molG+TSAdcock, Baran, et al., 2005gas phase; Entropy of acidity reassigned at 24 eu; authors did not take symmetry changes into account
Quantity Value Units Method Reference Comment
Deltar337.4 ± 2.0kcal/molCIDCAdcock, Baran, et al., 2005gas phase; Entropy of acidity reassigned at 24 eu; authors did not take symmetry changes into account

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adcock, Baran, et al., 2005
Adcock, W.; Baran, Y.; Filippi, A.; Speranza, M.; Trout, N.A., Polar substituent effects in the bicyclo[1.1.1]pentane ring system: Acidities of 3-substituted bicyclo[1.1.1]pentane-1-carboxylic acids, J. Org. Chem., 2005, 70, 3, 1029-1034, https://doi.org/10.1021/jo040236b . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References