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MeNH anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH4N- + Hydrogen cation = Methylamine

By formula: CH4N- + H+ = CH5N

Quantity Value Units Method Reference Comment
Deltar402.0 ± 2.6kcal/molD-EARadisic, Xu, et al., 2002gas phase
Deltar403.21 ± 0.82kcal/molG+TSMacKay, Hemsworth, et al., 1976gas phase
Quantity Value Units Method Reference Comment
Deltar394.5 ± 2.7kcal/molH-TSRadisic, Xu, et al., 2002gas phase
Deltar395.70 ± 0.70kcal/molIMREMacKay, Hemsworth, et al., 1976gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CH4N- + Hydrogen cation = Methylamine

By formula: CH4N- + H+ = CH5N

Quantity Value Units Method Reference Comment
Deltar402.0 ± 2.6kcal/molD-EARadisic, Xu, et al., 2002gas phase
Deltar403.21 ± 0.82kcal/molG+TSMacKay, Hemsworth, et al., 1976gas phase
Quantity Value Units Method Reference Comment
Deltar394.5 ± 2.7kcal/molH-TSRadisic, Xu, et al., 2002gas phase
Deltar395.70 ± 0.70kcal/molIMREMacKay, Hemsworth, et al., 1976gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Radisic, Xu, et al., 2002
Radisic, D.; Xu, S.J.; Bowen, K.H., Photoelectron spectroscopy of the anions, CH3NH- and (CH3)(2)N- and the anion complexes, H-(CH3NH2) and (CH3)(2)N-[(CH3)(2)NH), Chem. Phys. Lett., 2002, 354, 1-2, 9-13, https://doi.org/10.1016/S0009-2614(01)01470-1 . [all data]

MacKay, Hemsworth, et al., 1976
MacKay, G.J.; Hemsworth, R.S.; Bohme, D.K., Absolute gas-phase acidities of CH3NH2, C2H5NH2, (CH3)2NH, and (CH3)3N, Can. J. Chem., 1976, 54, 1624. [all data]


Notes

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