nC5H11S anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C5H11S- + Hydrogen cation = 1-Pentanethiol

By formula: C5H11S- + H+ = C5H12S

Quantity Value Units Method Reference Comment
Δr352.5 ± 2.4kcal/molD-EAJanousek, Reed, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Δr346.2 ± 2.5kcal/molH-TSJanousek, Reed, et al., 1980gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.090 ± 0.020LPDJanousek, Reed, et al., 1980 

Protonation reactions

C5H11S- + Hydrogen cation = 1-Pentanethiol

By formula: C5H11S- + H+ = C5H12S

Quantity Value Units Method Reference Comment
Δr352.5 ± 2.4kcal/molD-EAJanousek, Reed, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Δr346.2 ± 2.5kcal/molH-TSJanousek, Reed, et al., 1980gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Janousek, Reed, et al., 1980
Janousek, B.K.; Reed, K.J.; Brauman, J.I., Electron photodetachment from mercaptyl anions (RS- electron affinities of mercaptyl radicals and the S-H bond strength in mercaptans), J. Am. Chem. Soc., 1980, 102, 3125. [all data]


Notes

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