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H2NS anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

H2NS- + Hydrogen cation = H3NS

By formula: H2NS- + H+ = H3NS

Quantity Value Units Method Reference Comment
Deltar356.9 ± 3.1kcal/molG+TSDePuy and Bierbaum, 1981gas phase; Between CF3CH2OH and H2S, comparable to MeSH; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar350.6 ± 3.0kcal/molIMRBDePuy and Bierbaum, 1981gas phase; Between CF3CH2OH and H2S, comparable to MeSH; value altered from reference due to change in acidity scale
Deltar353.7 ± 3.0kcal/molIMRBBierbaum, Grabowski, et al., 1984gas phase; NH2- + COS ->.

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

H2NS- + Hydrogen cation = H3NS

By formula: H2NS- + H+ = H3NS

Quantity Value Units Method Reference Comment
Deltar356.9 ± 3.1kcal/molG+TSDePuy and Bierbaum, 1981gas phase; Between CF3CH2OH and H2S, comparable to MeSH; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar350.6 ± 3.0kcal/molIMRBDePuy and Bierbaum, 1981gas phase; Between CF3CH2OH and H2S, comparable to MeSH; value altered from reference due to change in acidity scale
Deltar353.7 ± 3.0kcal/molIMRBBierbaum, Grabowski, et al., 1984gas phase; NH2- + COS ->.

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy and Bierbaum, 1981
DePuy, C.H.; Bierbaum, V.M., Gas phase sulfur anions: Synthesis and reactions of H2NS- and related ions, Tetrahedron Lett., 1981, 22, 5129. [all data]

Bierbaum, Grabowski, et al., 1984
Bierbaum, V.M.; Grabowski, J.J.; DePuy, C.H., Gas-phase synthesis and reactions of nitrogen- and sulfur-containing anions, J. Phys. Chem., 1984, 88, 1389. [all data]


Notes

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