(MeOH){H2O}2..Cl anion
- Formula: CH8ClO3-
- Molecular weight: 103.526
- Information on this page:
- Other data available:
- Options:
Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -256.27 | kcal/mol | Ther | Evans and Keesee, 1991 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
H4ClO2- + + 2
= CH8ClO3-
By formula: H4ClO2- + CH4O + 2H2O = CH8ClO3-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.40 ± 0.20 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase |
| ΔrH° | 11.40 ± 0.30 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; For solvation by MeOH of core ion |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 5.80 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase |
| ΔrG° | 6.00 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; For solvation by MeOH of core ion |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Evans and Keesee, 1991
Evans, D.H.; Keesee, R.G.,
Thermodynamics of Gas-Phase Mixed-Solvent Cluster Ions - Water and Methanol on K+ and Cl- and Comparison to Liquid Solutions,
J. Phys. Chem., 1991, 95, 9, 3558, https://doi.org/10.1021/j100162a024
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.