(H2O)4..N3 anion
- Formula: H8N3O4-
- Molecular weight: 114.0818
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
H8N3O4- + 5 = H10N3O5-
By formula: H8N3O4- + 5H2O = H10N3O5-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 15.5 | kJ/mol | N/A | Yang, Kiran, et al., 2004 | gas phase; Affinity: EA change from (H2O)n-1..N3- ion. Vertical Detachment Energy: 4.85±0.06 eV |
H6N3O3- + 4 = H8N3O4-
By formula: H6N3O3- + 4H2O = H8N3O4-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 32.6 | kJ/mol | N/A | Yang, Kiran, et al., 2004 | gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 4.63±0.06 eV |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Yang, Kiran, et al., 2004
Yang, X.; Kiran, B.; Wang, X.B.; Wang, L.S.; Mucha, M.; Jungwirth, P.,
Solvation of the azide anion (N-3(-)) in water clusters and aqueous interfaces: A combined investigation by photoelectron spectroscopy, density functional calculations, and molecular dynamic,
J. Phys. Chem. A, 2004, 108, 39, 7820-7826, https://doi.org/10.1021/jp0496396
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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