(EtNO2)3..EtNO2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H15N3O6- + 3Ethane, nitro- = C8H20N4O8-

By formula: C6H15N3O6- + 3C2H5NO2 = C8H20N4O8-

Quantity Value Units Method Reference Comment
Δr13.60 ± 0.30kcal/molTDAsWincel, 2004gas phase
Quantity Value Units Method Reference Comment
Δr4.70kcal/molTDAsWincel, 2004gas phase

C8H20N4O8- + 4Ethane, nitro- = C10H25N5O10-

By formula: C8H20N4O8- + 4C2H5NO2 = C10H25N5O10-

Quantity Value Units Method Reference Comment
Δr11.90 ± 0.50kcal/molTDAsWincel, 2004gas phase
Quantity Value Units Method Reference Comment
Δr2.10kcal/molTDAsWincel, 2004gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.90 ± 0.20LPESStokes, Bowen, et al., 2008Vertical Detachment Energy: 2.3±0.1 eV

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C6H15N3O6- + 3Ethane, nitro- = C8H20N4O8-

By formula: C6H15N3O6- + 3C2H5NO2 = C8H20N4O8-

Quantity Value Units Method Reference Comment
Δr13.60 ± 0.30kcal/molTDAsWincel, 2004gas phase
Quantity Value Units Method Reference Comment
Δr4.70kcal/molTDAsWincel, 2004gas phase

C8H20N4O8- + 4Ethane, nitro- = C10H25N5O10-

By formula: C8H20N4O8- + 4C2H5NO2 = C10H25N5O10-

Quantity Value Units Method Reference Comment
Δr11.90 ± 0.50kcal/molTDAsWincel, 2004gas phase
Quantity Value Units Method Reference Comment
Δr2.10kcal/molTDAsWincel, 2004gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wincel, 2004
Wincel, H., Gas-phase clustering reactions of NO2-, C2H3NO2-, C2H4NO2-C2H5NO2- and C2H5NO4- with C2H5NO2, Int. J. Mass Spectrom., 2004, 232, 2, 185-194, https://doi.org/10.1016/j.ijms.2004.01.003 . [all data]

Stokes, Bowen, et al., 2008
Stokes, S.T.; Bowen, K.H.; Sommerfeld, T.; Ard, S.; Mirsaleh-Kohan, N.; Steill, J.D.; Compton, R.N., Negative ions of nitroethane and its clusters, J. Chem. Phys., 2008, 129, 6, 064308, https://doi.org/10.1063/1.2965534 . [all data]


Notes

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