nPrCH=C(Me)O anion


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H11O- + Hydrogen cation = 2-Hexanone

By formula: C6H11O- + H+ = C6H12O

Quantity Value Units Method Reference Comment
Δr1531. ± 8.8kJ/molTDEqBurkell, Fridgen, et al., 2003gas phase
Quantity Value Units Method Reference Comment
Δr1501. ± 8.4kJ/molTDEqBurkell, Fridgen, et al., 2003gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C6H11O- + Hydrogen cation = 2-Hexanone

By formula: C6H11O- + H+ = C6H12O

Quantity Value Units Method Reference Comment
Δr1531. ± 8.8kJ/molTDEqBurkell, Fridgen, et al., 2003gas phase
Quantity Value Units Method Reference Comment
Δr1501. ± 8.4kJ/molTDEqBurkell, Fridgen, et al., 2003gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Burkell, Fridgen, et al., 2003
Burkell, J.L.; Fridgen, T.D.; McMahon, T.B., Gas-phase acidities and sites of deprotonation of 2-ketones and structures of the corresponding enolates, Int. J. Mass Spectrom., 2003, 227, 3, 497-508, https://doi.org/10.1016/S1387-3806(03)00102-7 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References