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NCCH2CO2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(C3H2NO2- bullet Water) + Water = (C3H2NO2- bullet 2Water)

By formula: (C3H2NO2- bullet H2O) + H2O = (C3H2NO2- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Deltar21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K

C3H2NO2- + Water = (C3H2NO2- bullet Water)

By formula: C3H2NO2- + H2O = (C3H2NO2- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar59.83kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Deltar29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K

C3H2NO2- + Hydrogen cation = Acetic acid, cyano-

By formula: C3H2NO2- + H+ = C3H3NO2

Quantity Value Units Method Reference Comment
Deltar1382. ± 8.8kJ/molG+TSTaft and Topsom, 1987gas phase
Quantity Value Units Method Reference Comment
Deltar1354. ± 8.4kJ/molIMRETaft and Topsom, 1987gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
4.18 ± 0.16D-EATaft and Topsom, 1987 

Protonation reactions

C3H2NO2- + Hydrogen cation = Acetic acid, cyano-

By formula: C3H2NO2- + H+ = C3H3NO2

Quantity Value Units Method Reference Comment
Deltar1382. ± 8.8kJ/molG+TSTaft and Topsom, 1987gas phase
Quantity Value Units Method Reference Comment
Deltar1354. ± 8.4kJ/molIMRETaft and Topsom, 1987gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C3H2NO2- + Water = (C3H2NO2- bullet Water)

By formula: C3H2NO2- + H2O = (C3H2NO2- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar59.83kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Deltar29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K

(C3H2NO2- bullet Water) + Water = (C3H2NO2- bullet 2Water)

By formula: (C3H2NO2- bullet H2O) + H2O = (C3H2NO2- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Deltar21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Taft and Topsom, 1987
Taft, R.W.; Topsom, R.D., The Nature and Analysis of Substituent Effects, Prog. Phys. Org. Chem., 1987, 16, 1. [all data]


Notes

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