Et2NO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C4H10NO- + Hydrogen cation = Diethylhydroxylamine

By formula: C4H10NO- + H+ = C4H11NO

Quantity Value Units Method Reference Comment
Δr1551. ± 8.8kJ/molG+TSBartmess, Basso, et al., 1983gas phase; See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values
Quantity Value Units Method Reference Comment
Δr1523. ± 8.4kJ/molIMREBartmess, Basso, et al., 1983gas phase; See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.54 ± 0.13D-EABartmess, Basso, et al., 1983See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values

Protonation reactions

C4H10NO- + Hydrogen cation = Diethylhydroxylamine

By formula: C4H10NO- + H+ = C4H11NO

Quantity Value Units Method Reference Comment
Δr1551. ± 8.8kJ/molG+TSBartmess, Basso, et al., 1983gas phase; See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values
Quantity Value Units Method Reference Comment
Δr1523. ± 8.4kJ/molIMREBartmess, Basso, et al., 1983gas phase; See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bartmess, Basso, et al., 1983
Bartmess, J.E.; Basso, T.; eorgiadis, R.M., The electron affinity of a nitroxide radical, J. Phys. Chem., 1983, 87, 912. [all data]

Mahoney, Mendenhall, et al., 1973
Mahoney, L.R.; Mendenhall, G.D.; Ingold, K.U., Calorimetric and Equilibrium Studies on Some Stable Nitroxide and Iminoxy Radicals. Approximate O-H BDEs in Hydroxylamines and Oximes., J. Am. Chem. Soc., 1973, 95, 26, 8610, https://doi.org/10.1021/ja00807a018 . [all data]

Bordwell and Liu, 1996
Bordwell, F.G.; Liu, W.-Z., Solvent Effects on Homolytic Bond Dissociation Energies of Hydroxylic Acids, J. Am. Chem. Soc., 1996, 118, 44, 10819-10823, https://doi.org/10.1021/ja961469q . [all data]


Notes

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