Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

adeninide anion


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

adeninide anion + Hydrogen cation = Adenine

By formula: C5H4N5- + H+ = C5H5N5

Quantity Value Units Method Reference Comment
Deltar1402. ± 9.2kJ/molG+TSSharma and Lee, 2002gas phase; Acidity at N-9(imidazole N)
Quantity Value Units Method Reference Comment
Deltar1372. ± 8.4kJ/molIMRBSharma and Lee, 2002gas phase; Acidity at N-9(imidazole N)
Deltar1441. ± 17.kJ/molIMRBSharma and Lee, 2002gas phase; Less acidic N-10 site(aniline)

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sharma and Lee, 2002
Sharma, S.; Lee, J.K., Acidity of adenine and adenine derivatives and biological implications. A computational and experimental gas-phase study, J. Org. Chem., 2002, 67, 24, 8360-8365, https://doi.org/10.1021/jo0204303 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References