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adeninide anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

adeninide anion + Hydrogen cation = Adenine

By formula: C5H4N5- + H+ = C5H5N5

Quantity Value Units Method Reference Comment
Deltar1402. ± 9.2kJ/molG+TSSharma and Lee, 2002gas phase; Acidity at N-9(imidazole N)
Quantity Value Units Method Reference Comment
Deltar1372. ± 8.4kJ/molIMRBSharma and Lee, 2002gas phase; Acidity at N-9(imidazole N)
Deltar1441. ± 17.kJ/molIMRBSharma and Lee, 2002gas phase; Less acidic N-10 site(aniline)

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sharma and Lee, 2002
Sharma, S.; Lee, J.K., Acidity of adenine and adenine derivatives and biological implications. A computational and experimental gas-phase study, J. Org. Chem., 2002, 67, 24, 8360-8365, https://doi.org/10.1021/jo0204303 . [all data]


Notes

Go To: Top, Gas phase ion energetics data, References