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3-tBu-bicyclo[1.1.1]pentan-1-ide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C9H15- + Hydrogen cation = C9H16

By formula: C9H15- + H+ = C9H16

Quantity Value Units Method Reference Comment
Deltar408.50 ± 0.90kcal/molBranReed, Kass, et al., 2002gas phase
Quantity Value Units Method Reference Comment
Deltar400.7 ± 1.0kcal/molH-TSReed, Kass, et al., 2002gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reed, Kass, et al., 2002
Reed, D.R.; Kass, S.R.; Mondanaro, K.R.; Dailey, W.P., Formation of a 1-bicyclo[1.1.1]pentyl anion and an experimental determination of the acidity and C-H bond dissociation energy of 3-tert-butylbicyclo[1.1.1]pentane, J. Am. Chem. Soc., 2002, 124, 11, 2790-2795, https://doi.org/10.1021/ja0121890 . [all data]


Notes

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