(H2O)2..COS radical anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH2O2S- + 2Water = CH4O3S-

By formula: CH2O2S- + 2H2O = CH4O3S-

Quantity Value Units Method Reference Comment
Δr44.8 ± 8.4kJ/molN/ASurber and Sanov, 2002gas phase; Stated electron affinity is the Vertical Detachment Energy

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.530 ± 0.070LPESSurber and Sanov, 2002Stated electron affinity is the Vertical Detachment Energy

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH2O2S- + 2Water = CH4O3S-

By formula: CH2O2S- + 2H2O = CH4O3S-

Quantity Value Units Method Reference Comment
Δr44.8 ± 8.4kJ/molN/ASurber and Sanov, 2002gas phase; Stated electron affinity is the Vertical Detachment Energy

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Surber and Sanov, 2002
Surber, E.; Sanov, A., Photoelectron imaging spectroscopy of molecular and cluster anions: CS2- and OCS-(H2O)(1,2), J. Chem. Phys., 2002, 116, 14, 5921-5924, https://doi.org/10.1063/1.1467916 . [all data]


Notes

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