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FCH2CH2O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H4FO- + Hydrogen cation = Ethanol, 2-fluoro-

By formula: C2H4FO- + H+ = C2H5FO

Quantity Value Units Method Reference Comment
Deltar371.2 ± 2.9kcal/molG+TSGraul, Schnute, et al., 1990gas phase
Quantity Value Units Method Reference Comment
Deltar364.6 ± 2.8kcal/molCIDCGraul, Schnute, et al., 1990gas phase
Deltar363.5 ± 3.5kcal/molIMRBClair and McMahon, 1980gas phase; Between HF and acetone; value altered from reference due to change in acidity scale
Deltar364.9 ± 3.4kcal/molIMRBDawson and Jennings, 1977gas phase; Between HF and acetone; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Graul, Schnute, et al., 1990
Graul, S.T.; Schnute, M.E.; Squires, R.R., Gas-Phase Acidities of Carboxylic Acids and Alcohols from Collision-Induced Dissociation of Dimer Cluster Ions, Int. J. Mass Spectrom. Ion Proc., 1990, 96, 2, 181, https://doi.org/10.1016/0168-1176(90)87028-F . [all data]

Clair and McMahon, 1980
Clair, R.L.; McMahon, T.B., An ion cyclotron resonance study of base-induced elimination reactions of fluorinated alcohols and unimolecular loss of HF from chemically activated fluoroalkoxide ions, Int. J. Mass Spectrom. Ion Phys., 1980, 33, 21. [all data]

Dawson and Jennings, 1977
Dawson, J.H.J.; Jennings, K.R., Relative gas phase acidities of some fluoroalcohols, Int. J. Mass Spectrom. Ion Phys., 1977, 25, 47. [all data]


Notes

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