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2,6-diCl-phenide anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C6H3Cl2- + Hydrogen cation = Benzene, 1,3-dichloro-

By formula: C6H3Cl2- + H+ = C6H4Cl2

Quantity Value Units Method Reference Comment
Deltar1565. ± 8.8kJ/molG+TSSchlosser, Marzi, et al., 2001gas phase; Acid: m-dichlorobenzene. Anion assigned based on ab initio calculations.
Quantity Value Units Method Reference Comment
Deltar1533. ± 8.4kJ/molIMRESchlosser, Marzi, et al., 2001gas phase; Acid: m-dichlorobenzene. Anion assigned based on ab initio calculations.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schlosser, Marzi, et al., 2001
Schlosser, M.; Marzi, E.; Cottet, F.; Buker, H.H.; Nibbering, N.M.M., The acidity of chloro-substituted benzenes: A comparison of gas phase, ab initio, and kinetic data, Chem. Eur. J., 2001, 7, 16, 3511-3516, https://doi.org/10.1002/1521-3765(20010817)7:16<3511::AID-CHEM3511>3.0.CO;2-U . [all data]


Notes

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