1,1,3,3-tetraMe-1,3-disila-2-azacyclopentanide anion
- Formula: C6H16NSi2-
- Molecular weight: 158.3695
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C6H16NSi2- + =
By formula: C6H16NSi2- + H+ = C6H17NSi2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1536. ± 8.8 | kJ/mol | G+TS | Higgins, Hinde, et al., 2001 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1504. ± 8.4 | kJ/mol | IMRE | Higgins, Hinde, et al., 2001 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Higgins, Hinde, et al., 2001
Higgins, P.R.; Hinde, R.J.; Grimm, D.T.; Bloor, J.E.; Bartmess, J.E.,
The geometric dependence of acidity: hexamethyldisilazide anion,
Int. J. Mass Spectrom., 2001, 210, 231-240, https://doi.org/10.1016/S1387-3806(01)00453-5
. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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