(CHCl3)2..Cl anion
- Formula: C2H2Cl7-
- Molecular weight: 274.209
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -133.33 | kcal/mol | Ther | Hiraoka, Mizuno, et al., 2001 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
CHCl4- + 2 = C2H2Cl7-
By formula: CHCl4- + 2CHCl3 = C2H2Cl7-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.70 | kcal/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 7.25 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase |
C2H2Cl7- + 3 = C3H3Cl10-
By formula: C2H2Cl7- + 3CHCl3 = C3H3Cl10-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.80 | kcal/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 5.24 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka, Mizuno, et al., 2001
Hiraoka, K.; Mizuno, T.; Iino, T.; Eguchi, D.; Yamabe, S.,
Characteristic changes of bond energies for gas-phase cluster ions of halide ions with methane and chloromethanes,
J. Phys. Chem. A, 2001, 105, 20, 4887-4893, https://doi.org/10.1021/jp010143n
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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