DO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

DO- + Deuterium cation = Deuterium oxide

By formula: DO- + D+ = D2O

Quantity Value Units Method Reference Comment
Δr391.160 ± 0.060kcal/molD-EASchulz, Mead, et al., 1982gas phase; Given: 1.822549(37) eV. Derived acidity is for DOH -> DO- + H+
Δr392.60 ± 0.10kcal/molD-EASchulz, Mead, et al., 1982gas phase; For D2O -> DO- + D+. BDE: 120.96±0.05 Qian, Song, et al., 2002 ΔSacid: 23.2
Quantity Value Units Method Reference Comment
Δr384.84 ± 0.16kcal/molH-TSSchulz, Mead, et al., 1982gas phase; Given: 1.822549(37) eV. Derived acidity is for DOH -> DO- + H+
Δr385.60 ± 0.10kcal/molH-TSSchulz, Mead, et al., 1982gas phase; For D2O -> DO- + D+. BDE: 120.96±0.05 Qian, Song, et al., 2002 ΔSacid: 23.2

DO- + Deuterium oxide = (DO- • Deuterium oxide)

By formula: DO- + D2O = (DO- • D2O)

Quantity Value Units Method Reference Comment
Δr26.80 ± 0.70kcal/molTDAsMeot-ner and Sieck, 1986gas phase
Δr22.5 ± 2.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr20.1 ± 1.1kcal/molTDAsMeot-ner and Sieck, 1986gas phase
Δr16.9 ± 2.0kcal/molTDAsArshadi and Kebarle, 1970gas phase

(DO- • 2Deuterium oxide) + Deuterium oxide = (DO- • 3Deuterium oxide)

By formula: (DO- • 2D2O) + D2O = (DO- • 3D2O)

Quantity Value Units Method Reference Comment
Δr15.1 ± 1.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr7.70kcal/molTDAsArshadi and Kebarle, 1970gas phase

(DO- • 3Deuterium oxide) + Deuterium oxide = (DO- • 4Deuterium oxide)

By formula: (DO- • 3D2O) + D2O = (DO- • 4D2O)

Quantity Value Units Method Reference Comment
Δr14.2 ± 1.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr5.50kcal/molTDAsArshadi and Kebarle, 1970gas phase

(DO- • 4Deuterium oxide) + Deuterium oxide = (DO- • 5Deuterium oxide)

By formula: (DO- • 4D2O) + D2O = (DO- • 5D2O)

Quantity Value Units Method Reference Comment
Δr14.1 ± 1.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr4.20kcal/molTDAsArshadi and Kebarle, 1970gas phase

(DO- • Deuterium oxide) + Deuterium oxide = (DO- • 2Deuterium oxide)

By formula: (DO- • D2O) + D2O = (DO- • 2D2O)

Quantity Value Units Method Reference Comment
Δr16.4 ± 1.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr10.70kcal/molTDAsArshadi and Kebarle, 1970gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

DO- + Deuterium oxide = (DO- • Deuterium oxide)

By formula: DO- + D2O = (DO- • D2O)

Quantity Value Units Method Reference Comment
Δr26.80 ± 0.70kcal/molTDAsMeot-ner and Sieck, 1986gas phase
Δr22.5 ± 2.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr20.1 ± 1.1kcal/molTDAsMeot-ner and Sieck, 1986gas phase
Δr16.9 ± 2.0kcal/molTDAsArshadi and Kebarle, 1970gas phase

(DO- • Deuterium oxide) + Deuterium oxide = (DO- • 2Deuterium oxide)

By formula: (DO- • D2O) + D2O = (DO- • 2D2O)

Quantity Value Units Method Reference Comment
Δr16.4 ± 1.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr10.70kcal/molTDAsArshadi and Kebarle, 1970gas phase

(DO- • 2Deuterium oxide) + Deuterium oxide = (DO- • 3Deuterium oxide)

By formula: (DO- • 2D2O) + D2O = (DO- • 3D2O)

Quantity Value Units Method Reference Comment
Δr15.1 ± 1.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr7.70kcal/molTDAsArshadi and Kebarle, 1970gas phase

(DO- • 3Deuterium oxide) + Deuterium oxide = (DO- • 4Deuterium oxide)

By formula: (DO- • 3D2O) + D2O = (DO- • 4D2O)

Quantity Value Units Method Reference Comment
Δr14.2 ± 1.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr5.50kcal/molTDAsArshadi and Kebarle, 1970gas phase

(DO- • 4Deuterium oxide) + Deuterium oxide = (DO- • 5Deuterium oxide)

By formula: (DO- • 4D2O) + D2O = (DO- • 5D2O)

Quantity Value Units Method Reference Comment
Δr14.1 ± 1.0kcal/molTDAsArshadi and Kebarle, 1970gas phase
Quantity Value Units Method Reference Comment
Δr4.20kcal/molTDAsArshadi and Kebarle, 1970gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schulz, Mead, et al., 1982
Schulz, P.A.; Mead, R.D.; Jones, P.L.; Lineberger, W.C., OH- and OD- threshold photodetachment, J. Chem. Phys., 1982, 77, 1153. [all data]

Qian, Song, et al., 2002
Qian, X.M.; Song, Y.; Lau, K.C.; Ng, C.Y.; Liu, J.B.; Chen, W.W.; He, G.Z., A pulsed field ionization photoelectron-photoion coincidence study of the dissociative photoionization process D2O+h nu - OD++D+e(-), Chem. Phys. Lett., 2002, 353, 1-2, 19-26, https://doi.org/10.1016/S0009-2614(01)01442-7 . [all data]

Meot-ner and Sieck, 1986
Meot-ner, M.; Sieck, L.W., Relative acidities of water and methanol, and the stabilities of the dimer adducts, J. Phys. Chem., 1986, 90, 6687. [all data]

Arshadi and Kebarle, 1970
Arshadi, M.; Kebarle, P., Hydration of OH- and O2- in the Gas Phase. Comparative Solvation of OH- by Water and the Hydrogen Halides. Effect of Acidity, J. Phys. Chem., 1970, 74, 7, 1483, https://doi.org/10.1021/j100702a015 . [all data]


Notes

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