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mCF3-C6H5SiMe2 anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C9H10F3Si- + Hydrogen cation = C9H11F3Si

By formula: C9H10F3Si- + H+ = C9H11F3Si

Quantity Value Units Method Reference Comment
Deltar1574. ± 9.2kJ/molG+TSIrie, Kikukawa, et al., 2001gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB
Quantity Value Units Method Reference Comment
Deltar1541. ± 8.4kJ/molIMREIrie, Kikukawa, et al., 2001gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Irie, Kikukawa, et al., 2001
Irie, M.; Kikukawa, K.; Shimizu, N.; Mishima, M., Gas-phase acidities of aryldimethylsilanes, J. Chem. Soc. Perkin Trans., 2001, 2, 6, 923-928, https://doi.org/10.1039/b100488n . [all data]


Notes

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